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Catalysis in β-elimination reactions

5. Salt catalysis in a nhydrous acetic acid

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Study has been made of the effect of LiOCOCH3, LiCl, LiClO4, KOCOCH3 and NaOCOCH3 on β-elimination kinetics.

  2. 2.

    A mechanism for β-elimination in anhydr. acetic acid containing various salts has been proposed.

  3. 3.

    Rate constants for the various steps in the proposed β-elimination mechanism have been calculated.

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Literature Cited

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Authors
  1. S. S. Yufit
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  2. I. A. Esikova
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  3. L. F. Romanushkina
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  4. V. F. Kucherov
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Additional information

N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow. Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2193–2197, October, 1976.

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Yufit, S.S., Esikova, I.A., Romanushkina, L.F. et al. Catalysis in β-elimination reactions. Russ Chem Bull 25, 2048–2052 (1976). https://doi.org/10.1007/BF02659513

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  • DOI: https://doi.org/10.1007/BF02659513

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