Skip to main content
Log in

Surface segregation in an engineering alloy: Hastelloy C-276

  • Published:
Metallurgical Transactions A Aims and scope Submit manuscript

Abstract

We have examined the surface composition of a cold-worked nickel-base superalloy, HASTELLOY C-276, by Auger electron spectroscopy. The alloy was subjected to annealing cycles at temperatures between 100 and 900°C. A number of elements, including C, N, O, P, S, and Si, segregated to the sample surface. The segregation behavior appears to be quite complex. Yet it can be understood in terms of five fundamental effects: kinetic limitations, thermodynamic temperature effects, cold-work annealing, depletion of trace impurities, and solute interactions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. W. Gibbs:Trans Conn. Acad. Sci. 1875/76. vol. 3, p. 108, 1877-78; p. 343.

    Google Scholar 

  2. C.L. Briant and S. K. Banerji:Int. Met. Rev., 1978, vol. 23, no. 4, p. 164.

    CAS  Google Scholar 

  3. L. A. Harris:J. Appl. Phys. 1968, vol 39, p. 1428.

    Article  CAS  Google Scholar 

  4. S. H. Overbury, P. A. Bertrand and G. A. Somorjai,Chem. Rev. 1975, vol. 75, p. 547.

    Article  CAS  Google Scholar 

  5. S. Hofman and J. Erlewein:Scr. Met, 1978, vol. 10, p. 857.

    Article  Google Scholar 

  6. J. J. Burton, C. R. Helms and R. S. Polizzotti,J. Vac. Sci. Technol, 1976, vol. 13, p. 204.

    Article  CAS  Google Scholar 

  7. M. P. Seah and C. Lea:Phil. Mag., 1975, vol. 31, p. 627.

    CAS  Google Scholar 

  8. L. E. Davis, N. C. MacDonald, P. W. Palmberg, G. E. Riach, and R. E. Weber:Handbook of Auger Electron Spectroscopy, 2nd ed., Physical Electronics Ind., Eden Prairie, Minn., 1976.

    Google Scholar 

  9. J.C. Riviere:Cont.Phys., 1975, vol. 14, p. 513.

    Article  Google Scholar 

  10. J. A. Schwarz, R. S. Polizzotti, and J. J. Burton:Surf. Sci., 1977, vol. 67, pp. 429–36.

    Article  CAS  Google Scholar 

  11. Paul G. Shewmon:Diffusion In Solids, Chapter 6, McGraw Hill, New York, 1963.

    Google Scholar 

  12. B. Rüssel and P. Vela:Phil. Mag, 1963, vol. 8, p. 677.

    Google Scholar 

  13. H. P. Seah and C. Lea:Phil. Mag., 1975, vol. 31, p. 627.

    CAS  Google Scholar 

  14. M. Guttmann:Surf. Sci., 1975, vol. 53, p. 213.

    Article  CAS  Google Scholar 

  15. J. J. Burton and E. S. Machlin,phys. Rev. Lett., 1976, vol. 37, p. 1433.

    Article  CAS  Google Scholar 

  16. J. J. Burton:Surf Sci., in press.

Download references

Author information

Authors and Affiliations

Authors

Additional information

Formerly with Exxon Production Research Company

Rights and permissions

Reprints and permissions

About this article

Cite this article

Burton, J.J., Berkowitz, B.J. & Kane, R.D. Surface segregation in an engineering alloy: Hastelloy C-276. Metall Trans A 10, 677–682 (1979). https://doi.org/10.1007/BF02658388

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02658388

Keywords

Navigation