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The influence of oxidation-sirtl etch condition on the stacking fault generation in (111) silicon wafers

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Abstract

The successive oxidation-Sirtl etch technique has been investigated to evaluate the perfection of silicon crystals by detecting extrinsic stacking faults produced during oxidation. Experiments were performed in (111) epitaxial wafers. Measured densities of stacking faults were found to epend on the conditions of thermal oxidation, and stacking fault densities were a maximum at an oxidation temperature of around 1100°C. The stacking fault densities were reduced appreciably when epitaxial wafers were chemically etched to remove several tens of microns prior to the test. The generation of stacking faults is thought to occur by heterogeneous nucleation due to a very small amount of unidentified impurity found in epitaxial crystals.

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References

  1. W. A. Fisher and J. A. Amick, "Defect Structure on Silicon Surfaces After Thermal Oxidation", Journal of the Electrochemical Society, Vol. 113, 1966, pp. 1054–1060.

    CAS  Google Scholar 

  2. A. Mayer, "Detection of Damage on Silicon Surface: Origin and Propagation of Defects," RCA Review, Vol. 31, 1970, pp. 414–430.

    CAS  Google Scholar 

  3. G. R. Booker and W, J. Tunstal, "Diffraction Contrast Analysis of Two-Dimensional Defects Present in Silicon After Annealing," Philosophical Magazine, Vol. 13, 1966, pp. 71–83.

    CAS  Google Scholar 

  4. M. L. Joshi, "Stacking Faults in Steam-Oxidized Silicon," Acta Metallurgica, Vol. 14, 1966, pp. 1157–1172.

    Article  CAS  Google Scholar 

  5. R. J. Jaccodine and C. M. Drum, "Extrinsic Stacking Faults in Silicon After Heating in Wet Oxygen," Applied Physics Letters, Vol. 8, 1966, pp. 29–30.

    Article  CAS  Google Scholar 

  6. D. J. D. Thomas, "Surface Damage and Copper Precipitation in Silicon," Physica Status Solidi, Vol. 3, 1963, pp. 2261–2273.

    CAS  Google Scholar 

  7. H. J. Queisser and P. G. G. van Loon, "Growth of Lattice Defects in Silicon During Oxidation," Journal of Applied Physics, Vol. 35, 1964, pp. 3066–3067.

    Article  CAS  Google Scholar 

  8. D. I. Pomerantz, "Effects of Grown-In and Process-Induced Defects in Single Crystal Silicon," Journal of the Electrochemical Society, Vol. 119, 1972, pp. 255–265.

    Article  CAS  Google Scholar 

  9. K. V. Ravi and C. J. Varker, "Oxidation-Induced Stacking Faults in Silicon. 1. Nucleation Phenomenon," Journal of Applied Physics, Vol. 45, 1974, pp. 263–271.

    Article  CAS  Google Scholar 

  10. C. M. Drum and W. van Gelder, "Stacking Faults in (100) Epitaxial Silicon Caused by HF and Thermal Oxidation and Effects on p-n Junctions," Journal of Applied Physics, Vol. 43, 1972, pp. 4465–4468.

    Article  CAS  Google Scholar 

  11. C. M. Hsieh and D. M. Maher, "Nucleation and Growth of Stacking Faults in Epitaxial Silicon During Thermal Oxidation," Journal of Applied Physics, Vol. 44, 1973, pp. 1302–1306.

    Article  CAS  Google Scholar 

  12. S. Prussin, "Generation of Stacking Faults and Dislocation Loops in Silicon Wafers," Journal of Applied Physics, Vol. 43, 1972, pp. 733–735.

    Article  CAS  Google Scholar 

  13. S. Prussin, "Generation of Stacking Faults and Prismatic Dislocation Loops in Device-Processed Silicon Wafers," Journal of Applied Physics, Vol. 43, 1972, pp. 2850–2856.

    Article  CAS  Google Scholar 

  14. J. E. Lawrence, "Stacking Faults in Annealed Silicon Surfaces," Journal of Applied Physics, Vol. 40, 1969, pp. 360–365.

    Article  Google Scholar 

  15. E. Sirtl and A. Adler, "ChromsÄure-FlussÄure als Spezifisches System zur Ätzgrubenentwicklung auf Silizium," Zeitschrift für Metallkunde, Vol. 52, 1961, pp. 529–531.

    CAS  Google Scholar 

  16. Y. Sugita, "X-Ray Observations of Defect Structures in Silicon Crystals," Japan Journal of Applied Physics, Vol. 4, 1965, pp. 962–972.

    Article  CAS  Google Scholar 

  17. A. H. Cottrell, "An Introduction to Metallurgy," (Edward Arnold Ltd.) Chap. 7, 1967.

  18. F. A. Huntley and A. F. W. Willoughby, "Surface Diffsion of Gold on Silicon," Solid-State Electronics, Vol. 14, 1971, pp. 641–643.

    Article  CAS  Google Scholar 

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Sugita, Y., Aoshima, T., Yoneda, K. et al. The influence of oxidation-sirtl etch condition on the stacking fault generation in (111) silicon wafers. J. Electron. Mater. 4, 175–189 (1975). https://doi.org/10.1007/BF02657843

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  • DOI: https://doi.org/10.1007/BF02657843

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