Abstract
Leaching of attritor-ground chalcopyrite concentrate by acidified ferric sulfate, generatedin situ, has been studied. Air and oxygen alone and mixed with sulfur dioxide were tested as oxidizing agents. A specially designed reactor, which allowedn situ oxidation of ferrous sulfate, permitted the leaching of a 20 pct solids slurry with high copper recovery. The leachate contained ~ 53 g/l copper, a high enough concentration that solvent extraction may not be necessary.
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R. J. Roman and B. R. Benner:Miner. Sci. Eng., 1973, vol. 5, no. 1, pp. 3–24.
M. C. Kuhn, N. Arbiter, and H. Kling:CIM Bull, 1991, vol. 67, no. 742, pp. 62–73.
Anonymous:Eng. Min. J., 1977, vol. 178, no. 11, p. 27.
H. M. Brennecke, 0. Bergmann, R. R. Ellefson, D. S. Davies, R. E. Lueders, and R. A. Spitz: Unpublished research, Kennecott Copper Corporation, Ledgemont Laboratory, Lexington, MA, presented at AIME Annual Meeting, Denver, CO, 1978.
M. C. Sze:Eng. Min. J., 1977, vol. 178, no. 10, p. 100.
P. B. Munoz: Ph.D. Thesis, The University of Utah, Salt Lake City, August 1977.
L. W. Beckstead, P. B. Munoz, J. L. Sepulved, J. A. Herbst, J. D. Miller, F. A. Olson, and M. E. Wadsworth:Extractive Metallurgy of Copper, vol. 2, pp. 612–32, TMS-AIME, NY, 1976.
E. S. Leaver and R. V. Thurston: Bureau of Mines Report of Investigation, Ser. No. 2556, 1923.
G. L. Oldright, H. E. Keyes, and F. S. Wartman:Trans. AIME, 1926, vol. 73, pp. 84–107.
The International Nickel Company of Canada, Belgium Patent No. 828,218, August 22, 1974.
W. C. E. Higginson and J. W. Marshll: J. Chem. Soc, 1957, pp. 447–58.
W. F. Wyman and S. F. R vitz: Bureau of Mines Report of Investigation, Ser. No. 4077, 1947.
B. L. Tiwari, J. Kolbe, nd H. W. H yden, Jr.: Unpublished research, Martin Mariett Corporation, Martin Mariett Laboratories, Baltimore, MD, 1978.
. R. Gordon and R. W. Pickering:Met. Trans. B, 1975, vol. 6B, pp. 43–53.
J. D. Sullivn:Trans. AIME, 1933, vol. 106, pp. 515–46.
J. E. Dutrizc, R. J. C. MacDonald, and T. R. Ingraham:Trans. TMS-AIME, 1969, vol. 245, pp. 955–59.
D. L. Jones and E. Pcters:Extractive Metallurgy of Copper, vol. 2, pp. 633–53, TMS-IME, NY, 1976.
D. Verhulst: Eng. Sc.D. Thesis, Columbia University, New York City, NY, 1974.
B. L. Tiwari: Eng. Sc.D. Thesis, Columbia University, New York City, NY, 1976.
M. E. Wadsworth: Private communication, University of Utah, Salt Lake City, 1977.
M. Cher and N. Davidson:J. mer. Chem. Soc, 1955, vol. 77, pp. 793–98.
A. Viszolyi, H. Veltman, I. H. Warren, and V. N. Mackiw:J. Metals, 1967, vol. 19, no. 11, pp. 52–58.
F. Forward and V. N. Mackiw:Trans. AIME, 1955, vol. 203, pp. 457–563.
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formerly with Martin Mariett Laboratories
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Tiwari, B.L., Kolbe, J. & Hayden, H.W. Leaching of high-solids, attritor-ground chalcopyrite concentrate byin situ generated ferric sulfate solution. Metall Trans B 11, 89–93 (1980). https://doi.org/10.1007/BF02657176
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DOI: https://doi.org/10.1007/BF02657176