Abstract
The change in hydrogen concentration as a function of applied strain has been studied in commercial titanium alloys that included threeβ-phase, twoα-phase, and an (α + β)-phase Ti-6Al-4V alloy with differingα/β morphologies.Insitu measurements were made using a nondestructive nuclear technique on samples for which uniaxial compressive and tensile stresses were applied by four-point bending.
Theβ-phase alloys exhibited hydrogen redistribution under an elastic stress gradient, but no further change was discernible accompanying plastic deformation. The extent of hydrogen concentration change for theβ-phase alloys was of the order of 4 to 6 pct for a 620 MPa stress gradient. This is less than would be predicted based on available data for the partial molal volume of hydrogen. Diffusion coefficients in a stress gradient were also determined and are consistent with those measured inβ-phase titanium at elevated and room temperatures. Within the experimental sensitivities there was no evidence of hydrogen redistribution with applied stress for theα-phase and Ti-6Al-4V alloys.
Similar content being viewed by others
References
I. M. Bernstein and A. W. Thompson:Hydrogen in Metals, ASM, Metals Park, OH, 1974.
A. W. Thompson and I. M. Bernstein:Effect of Hydrogen on Behavior of Materials, AIME, New York, 1976.
H. H. Johnson, J. G. Morlet, and A. R. Troiano:Trans. TMS-AIME, 1958, vol. 212, p. 528.
A. R. Troiano:Trans. ASM, 1960, vol. 52, p. 54.
D. G. Westlake:Trans. ASM, 1969, vol. 62, p. 1000.
R. Dutton, K. Nuttal, M. P. Puls and L. A. Simpson:Met. Trans. A, 1977, vol. 8A,p. 1553.
J. C. M. Li, R. A. Oriani, and L. S. Darken:Z. Phys. Chem., Neue Folge, 1966, vol.49, p. 271.
R. A. Oriani:Proc. of Conference of Fundamental Aspects of Stress Corrosion Cracking, R. W. Staehle, A. J. Forty, and D. van Rooyen, eds., p. 32, NACE, Houston, TX, 1969.
J. O. M. Bockris and P. K. Subramanyan:Acta Metall., 1971, vol. 19, p. 1205.
R. Chopra and J. C. M. Li:Scr. Metall., 1972, vol. 6, p. 543.
H. A. Wriedt and R. A. Oriani:Acta Metall., 1970, vol. 18, p. 753.
J. O. M. Bockris, W. Beck, M. A. Genshawl, P. K. Subramanyan, and F. S. Williams:Acta Metall., 1971, vol. 19, p. 1209.
J. L. Waisman, G. Sines, and L. B. Robinson:Met. Trans., 1973, vol. 4, p. 291.
G. Schaumann, J. Volkl, and G. Alefeld:Phys. Status Solidi, 1970, vol. 42, p. 401.
P. N. Adler and R. L. Schulte:Scr. Metall., 1978, vol. 13, p. 669.
E. A. Kamykowski, F. J. Kuehne, E. J. Schneid, and R. L. Schulte:Nucl. Instrum. Methods, 1979, vol. 165, p. 573.
G. M. Padawer, D. J. Larson, Jr., and P. N. Adler:Met. Trans., 1971, vol. 2, p. 2287.
P. N. Adler, E. A. Kamykowski, and G. M. Padawer:Hydrogen in Metals, I. M. Bernstein and A. W. Thompson, eds., p. 623, ASM, Metals Park, OH, 1974.
N. E. Paton, O. Buck, and J. C. Williams:Scr. Metall., 1975, vol. 9, p. 687.
J. Crank:The Mathematics of Diffusion, p. 58, Clarendon Press, Oxford, 1956.
J. J. DeLuccia:Report No. NADC-76207-30, Naval Air Development Center, Warminster, PA, 1976.
R. J. Wasilewski and G. L. Kehl:Metallurgia, 1954, vol. 50, p. 225.
T. P. Papazoglou and M. T. Hepworth:Trans. TMS-AIME, 1968, vol. 242, p. 682.
D. L. Johnson and H. G. Nelson:Met. Trans., 1973, vol. 4, p. 569.
N. E. Paton and J. C. Williams:Hydrogen in Metals, I. M. Bernstein and A. W. Thompson, eds., p. 409, ASM, Metals Park, OH, 1974.
N. E. Paton and R. A. Spurting:Met. Trans. A, 1976, vol. 7A, p. 1769.
J. Jinoch, S. Ankem, and H. Margolin:Mater. Sci. Eng., 1978, vol. 34, p. 203.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Adler, P.N., Schulte, R.L., Schneid, E.J. et al. Stress induced hydrogen redistribution in commercial titanium alloys. Metall Trans A 11, 1617–1623 (1980). https://doi.org/10.1007/BF02654526
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02654526