Skip to main content
SpringerLink
Log in

Oxygen permeability of calcia-stabilized zirconia

  • Published:
Metallurgical Transactions B Aims and scope Submit manuscript

Abstract

Oxygen permeability of commercial calcia-stabilized zirconia has been measured at 1673 to 1823 K by the following cell; O2 ZrO2(CaO) N2 - O2 (P’tO2 = 1 atm) solid electrolyte (P″O2 = 0.39 - 1010-3 atm). Oxygen permeability of calcia-stabilized zirconia is proportional to (1 - P″O2 1/4). From the permeability measurement, the conduction properties of the electrolyte were log σ-‡ b+ = 0.28- 5100/T and logPb+ =-0.87 + 15,400/T where σ-‡ b+ is the þ-@#@ type electronic conductivity at PO 2 = 1 atm, and Pb+ is the oxygen activity at which the þ-@#@ type electronic conductivity and the ionic conductivity are equal.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. H. Etsell and S. N. Flengas:Met. Trans., 1972, vol. 3, pp. 27–36.

    Article  CAS  Google Scholar 

  2. M. Iwase, K. Fujimura, and T. Mori:J. Jap. Inst. Met., 1975, vol. 39, pp. 952–59.

    CAS  Google Scholar 

  3. M. Iwase and T. Mori:Metal-Slag-Gas Reactions and Processes, Z. A. Folouris and W. W. Smeltzer, eds., pp. 885–902, Electrochem. Soc. Inc., New Jersey, 1975.

    Google Scholar 

  4. A. W. Smith, F. W. Meszadors, and C. D. Amata:J. Amer. Ceram. Soc, 1966, vol. 49, pp. 240–44.

    Article  CAS  Google Scholar 

  5. W. A. Fischer:Fast Ion Transport in Solid-Solid State Batteries and Devices, W. W. Gool, ed., pp. 503–12, North-Holland Publishing Co., Amsterdam, 1972.

    Google Scholar 

  6. S. F. Palguev, V. K. Gildermann, and A. D. Neujimin:J. Electrochem. Soc, 1975, vol. 122, pp. 745–48.

    Article  CAS  Google Scholar 

  7. C. B. Alcock and J. C. Chan:Can. Met. Quart., 1972, vol. 11, pp. 559–67.

    Article  CAS  Google Scholar 

  8. K. Kitazawa and R. L. Coble:J. Amer. Ceram. Soc, 1974, vol. 57, p. 360.

    Article  CAS  Google Scholar 

  9. T. Takahashi, H. Iwahara, and I. Ito:Denki Kagaku, 1970, vol. 38, p. 288.

    Google Scholar 

  10. R. Hartung and H. H. Möbius:Z. Phys. Chem., 1970, vol. 243, pp. 133–38.

    CAS  Google Scholar 

  11. L. Hyenes and N. Beekman:Proc. Brit. Ceram. Soc, 1971, vol. 19, p. 229.

    Google Scholar 

  12. F. A. Kröger and H. J. Vink:Solid State Physics, F. Scitz and D. Turnbull, eds., vol. 3, p. 310, Academic Press, New York, 1956.

    Google Scholar 

  13. H. Schmalzried:Z. Phys. Chem., 1963, vol. 38, pp. 87–102.

    Article  CAS  Google Scholar 

  14. H. Schmalzried:Ber. Bunsenges, Phys. Chem., 1962, vol. 66, pp. 572–76.

    CAS  Google Scholar 

  15. R. M. Barrier:Diffusion in and Through Solids, p. 37, Cambridge University Press, New York, 1941;c.f. J. C.Crank: The Mathematics of Diffusion, p. 78, Oxford University Press, London, 1957.

    Google Scholar 

  16. L. N. Friedman, K. E. Oberg, W. M. Boorstein, and R. A. Rapp:Met. Trans., 1973, vol. 4, p. 69.

    Article  CAS  Google Scholar 

  17. J. W. Patterson, E. C. Bogren, and R. A. Rapp:J. Electrochem. Soc, 1967, vol. 114, pp. 752–58.

    Article  CAS  Google Scholar 

  18. K. S. Goto:Trans. Iron Steel Inst. Jap., 1976,vol. 16, p.470.

    Google Scholar 

  19. J. W. Patterson:J. Electrochem. Soc, 1971, vol. 118, pp. 1033–38.

    Article  CAS  Google Scholar 

  20. W. A. Fischer and W. Ackermann:Arch. Eisenhüttenw., 1965, vol. 36, p. 643.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Metallurgy, USA

    Masanori Iwase (Research Associate)

  2. Kyoto University, 606, Sakyo-ku, Kyoto, Japan

    Toshisada Mori (Member of AIME, Professor of Metallurgy)

Authors
  1. Masanori Iwase
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Toshisada Mori
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Iwase, M., Mori, T. Oxygen permeability of calcia-stabilized zirconia. Metall Trans B 9, 365–370 (1978). https://doi.org/10.1007/BF02654409

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02654409

Keywords

Search

Navigation