Abstract
The free energies of mixing in melts in the system 2FeO · SiO2-2MnO · SiO2 at 1450°C and the system 2.33FeO · TiO2-2.33MnO · TiO2 at 1475°C have been obtained from measurement of the equilibrium Mn + FeO = Fe + MnO established between the melts and ironmanganese foils. Both systems exhibit ideal silicate mixing. The phase diagram for the system 2FeO-SiO2-2MnO ·SiO2 is calculated.
Similar content being viewed by others
References
F. D. Richardson:Trans. Faraday Soc, 1956, vol. 52, p. 1312.
J. Lumsden:Physical Chemistry of Process Metallurgy, p. 165, Interscience, New York, 1961.
G. R. Belton, H. Suito, and D. R. Gaskell:Met. Trans., 1973, vol. 4, p. 2541.
K. Schwerdtfeger and A. Muan:Trans. TMS-AIME, 1966, vol. 236, p. 201.
P. T. Carter, B. Murad, and R. Hay:J. West. Scotland Iron and Steel Inst., 1952-53, vol. 60, p. 123.
R. L. Orr:J. Amer. Chem. Soc, 1953, vol. 75, p. 528.
H. B. Bell:JISI, 1963, vol. 201, p. 116.
U. V. Choudary, D. R. Gaskell, and G. R. Belton:Met. Trans. B, 1977, vol. 8B, p. 67.
I. C. Smith and H. B. Bell:Trans. I. M. M., 1971, vol. 80, p. C55.
E. B. Sandell:Colrimetric Metal Analysis, Interscience, 1965.
J. F. Elliott and M. Gleiser:Thermochemistry for Steelmaking, vol. 1, Addison-Wesley, Reading, Mass, 1960.
R. Schuhmann and P. J. Ensio:Trans. AIME, 1951, vol. 191, p. 401.
B. K. D. P. Rao and D. R. Gaskell: Unpublished research. Univ. of Pennsyl- vania, 1978.
R. Hultgren, P. D. Desai, D. T. Hawkins, M. Gleiser, and K. K. Kelley:Selected Values of the Thermodynamic Properties of Binary Alloys, p. 839, ASM, 1973.
R. A. Robie and D. R. Waldbaum: Geological Survey Bulletin 1259, U. S. Govt. Printing Office, 1968.
E. Martin and,H. B. Bell:Trans. I. M. M., 1974, vol. 83, p. C193.
I. C. Smith and H. B. Bell:Trans. I. M. M., 1970, vol. 79, p. C253.
J. B. MacChesney and A. Muan:Amer. Miner., 1961, vol. 46, p. 572.
J. V. Biggers and A. Muan:J. Amer. Ceramic Soc., 1967, vol. 50, p. 23
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Song, K.S., Gaskell, D.R. The free energies of mixing of melts in the systems 2FeO-SiO2-2MnO-SiO2 and 2.33FeO-TiO2-2.33MnOTiO2 . Metall Trans B 10, 15–20 (1979). https://doi.org/10.1007/BF02653966
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02653966