Skip to main content
Log in

On the stable Mg-Zn-Y quasicrystals

  • Published:
Metallurgical and Materials Transactions A Aims and scope Submit manuscript

Abstract

By the conventional air-cooled casting method, bulk ingots with a large fraction of stable Mg-Zn-Y icosahedral quasicrystals, both simple and face-centered, were obtained. The quasicrystal structures were directly confirmed by high-resolution electron microscopy (HREM) observations. The electron diffraction patterns from the quasicrystals were studied by computer simulations. A coexisting crys-talline phase of the quasicrystals was identified as the Mg7Zn3 phase, which was proved to be the (1/1) approximant of the quasicrystals. The quasicrystals were stable during a continuous heating process. However, at high temperature, oxidation occurred, and thus, Y2O3 and MgO products were formed. Oxidation at high temperatures is characteristic for the Mg-Zn-Y alloys and differs from Al-base alloys.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M.A. Marcus and V. Elser:Phil. Mag. Lett. B, 1986, vol. 54B, pp. 101–04.

    Google Scholar 

  2. P. Guyot and M. Audier:Mater. Sci. Forum, 1987, vols. 22-24, pp. 247–56.

    Article  CAS  Google Scholar 

  3. N. Yu, R. Portier, D. Gratias, K. Yu-Zhang, and J. Bigot:Mater. Sci. Forum, 1987, vols. 22-24, pp. 579–90.

    CAS  Google Scholar 

  4. A.P. Tsai, A. Inoue, and T. Masumoto:J. Mater. Sci. Lett., 1987, vol. 6, pp. 1403–05.

    Article  CAS  Google Scholar 

  5. L.X. He, Y.K. Wu, and K.H. Kuo: inQuasicrystals and Incommensurate Structures in Condensed Matter, M.J. Yacaman, D. Romeu, V. Castano, and A. Gomez, eds., World Scientific, Singapore, 1990, pp. 372–84.

    Google Scholar 

  6. B. Grushko:Phil. Mag. Lett, 1992, vol. 66, pp. 151–57.

    CAS  Google Scholar 

  7. S. Maamar and M. Harmelin:Phil. Mag. Lett., 1991, vol. 64, pp. 343–48.

    CAS  Google Scholar 

  8. C. Beeli, H.-U. Nissen, and J. Robadey:Phil. Mag. Lett., 1991, vol. 63, pp. 87–95.

    CAS  Google Scholar 

  9. A.P. Tsai, A. Inoue, and T. Masumoto:Phil. Mag. Lett., 1991, vol. 64, pp. 163–67.

    CAS  Google Scholar 

  10. W. Ohashi and F. Spaepen:Nature, 1987, vol. 330, pp. 555–56.

    Article  CAS  Google Scholar 

  11. F. Spaepen, L.C. Chen, S. Ebalard, and W. Ohashi:Proc. Anniversary Adriatico Research Conf. on Quasicrystals, M.V. Jaric and S. Lundqvist, eds., World Scientific, Singapore, 1990, pp. 1–18.

    Google Scholar 

  12. Z.P. Luo, S.Q. Zhang, Y.L. Tang, and D.S. Zhao:Scripta Metall. Mater., 1993, vol. 28, pp. 1513–18.

    Article  CAS  Google Scholar 

  13. Z.P. Luo and S.Q. Zhang:J. Mater. Sci. Lett, 1993, vol. 12, pp. 1490- 92.

    Google Scholar 

  14. Z.P. Luo and S.Q. Zhang:Acta Crystall. A., 1993, vol. 12A, suppl., p. 423.

    Article  Google Scholar 

  15. Z.P. Luo, S.Q. Zhang, Y.L. Tang, and D.S. Zhao:Scripta Metall. Mater., 1994, vol. 30, pp. 393–98.

    Article  CAS  Google Scholar 

  16. JCPDS File No. 8-269.

  17. S. Ebalard and F. Spaepen:J. Mater. Res., 1989, vol. 4, pp. 39–43.

    CAS  Google Scholar 

  18. A.I. Goldman, J.E. Shield, C.A. Guryan, and P.W. Stephens:Proc. Anniversary Adriatico Research Conf. on Quasicrystals, M.V. Jaric and S. Lundqvist, eds., World Scientific, Singapore, 1990, pp. 60–73.

    Google Scholar 

  19. J.E. Shield, L.S. Chumbley, R.W. McCallum, and A.I. Goldman:J. Mater. Res., 1993, vol. 8, pp. 44–48.

    CAS  Google Scholar 

  20. F.H. Li: inCrystal-Quasicrystal Transitions, M.J. Yacaman and M. Torres, eds., North-Holland, Amsterdam, 1993, pp. 13–47.

    Google Scholar 

  21. T.C. Lubensky, J.E.S. Socolar, P.J. Steinhardt, P.A. Bancel, and P.A. Heiney:Phys. Rev. Lett, 1986, vol. 57, pp. 1440–43.

    Article  CAS  Google Scholar 

  22. I. Higashi, N. Shiotani, M. Uda, T. Mizoguchi, and H. Katoh:J. Solid State Chem., 1981, vol. 36, pp. 225–33.

    Article  CAS  Google Scholar 

  23. Z.H. Chen, X.Y. Jiang, J.M. Xiao, and L.J. Wu:Scripta Metall. Mater., 1992, vol. 26, pp. 291–96.

    Article  CAS  Google Scholar 

  24. O. Kubaschewski and C.B. Alcock:Metallurgical Thermochemistry, Pergamon Press, Oxford, 1979, pp. 320 and 381.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Luo, Z.P., Sui, H.X. & Zhang, S.Q. On the stable Mg-Zn-Y quasicrystals. Metall Mater Trans A 27, 1779–1784 (1996). https://doi.org/10.1007/BF02651927

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02651927

Keywords

Navigation