Abstract
We have grown CdGeAs2 single crystals by chemical vapor transport (CVT), a method not previously applied for this compound. The crystallographic data of this chalcopyrite (cell parametersa 0 = 5.9456 ± 0.0001Å, c0 = 11.2131 ± 0.0007Å) and its electrical transport properties are reported. Predominantly n-type crystals are obtained (at RTn = 1 · 1017cm−3, μn = 2000 cm2(Vs)−1). Vacuum heat treatment at 500° C yields a type conversion fromn- to p-type. In all p-type samples the minority carrier mobility is calculated to be larger than 10000 cm2(Vs)−1.
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Baumgartner, F.P., Lux-Steiner, M. & Bucher, E. Growth of CdGeAs2 single crystals by the chemical vapor transport method. J. Electron. Mater. 19, 777–781 (1990). https://doi.org/10.1007/BF02651384
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DOI: https://doi.org/10.1007/BF02651384