Skip to main content
Log in

Ultraviolet light-driven epitaxial growth of gallium arsenide at reduced substrate temperatures

  • Published:
Journal of Electronic Materials Aims and scope Submit manuscript

    We’re sorry, something doesn't seem to be working properly.

    Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.

Abstract

We report on the photodeposition of gallium arsenide on gallium arsenide and silicon at low substrate temperatures utilizing ultraviolet radiation. A 1000 W Hg-Xe arc lamp serves as the light source with triethylgallium and arsine serving as the reactants. In this study, single crystal gallium arsenide thin films are obtained at substrate temperatures of approximately 357°. The electrical, chemical and structural properties of the photodeposited films are presented and the mechanisms involved in the deposition process are discussed. It is found that both photolytic and pyrolytic mechanisms are involved in the deposition process for the experimental conditions considered and that the desorption of excess arsenic is important in the low temperature growth of GaAs using photochemical means.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. V. M. Donnelly, V. R. McCrary, A. Applebaum, D. Brasen and W. P. Lowe, J. Appl. Phys.61, 1410 (1987).

    Article  CAS  Google Scholar 

  2. J. Nishizawa, Y. Kokubun, H. Shimawaki and M. Koike, J. Electrochem. Soc.132, 1939 (1985).

    Article  CAS  Google Scholar 

  3. J. Nishizawa, T. Kurabayashi and J. Hoshina, J. Electrochem. Soc.134, 502 (1987).

    Article  CAS  Google Scholar 

  4. J. J. Zinck, P. D. Brewer, J. E. Jensen, G. L. Olsen and L. W. Tutt, Mat. Res. Soc. Symp. Proc.75, 233 (1987).

    CAS  Google Scholar 

  5. H. Kukimoto, Y. Ban, H. Komatsu, M. Takechi and M. Ishizaki, J. Cryst. Growth,77, 223 (1986).

    Article  CAS  Google Scholar 

  6. S. M. Bedair, J. K. Whisnant, N. H. Karam, M. A. Tischler and T. Katsuyama, Appl. Phys. Lett.48, 174 (1986).

    Article  CAS  Google Scholar 

  7. Y. Aoyagi, M. Kanazawa, A. Doi, S. Iwai and S. Namba, J. Appl. Phys.60, 3131 (1986).

    Article  CAS  Google Scholar 

  8. W. Roth, H. Krautle, A. Krings and H. Beneking, Mat. Res. Soc. Symp. Proc.17, 193 (1983).

    CAS  Google Scholar 

  9. K. A. Jones, Solid State Technol.28, 151 (1985).

    Article  CAS  Google Scholar 

  10. I. A. Frolov, B. L. Druz, P. B. Boldyrevshii and E. B. Sokolov,Izv. Akad. Nauk SSSR Neorg. Mat.13, 906 (1977).

    CAS  Google Scholar 

  11. N. Putz, H. Heinecke, E. Veuhoff, G. Arens, M. Heyen, H.Luth and P. Balk, J. Cryst. Growth68, 194 (1984).

    Article  Google Scholar 

  12. D. P. Norton and P. K. Ajmera, Proc. SPIE945, 55 (1988).

    CAS  Google Scholar 

  13. C. Plass, H. Heinecke, O. Kayser, H. Luth and P. Balk, J. Cryst. Growth88, 455 (1988).

    Article  CAS  Google Scholar 

  14. M. Lax, J. Appl. Phys.48, 3919 (1977).

    Article  CAS  Google Scholar 

  15. M. Lax, Appl. Phys. Lett.33, 786 (1978).

    Article  Google Scholar 

  16. A. Kinrot, J. Bloch and Y. Zeiri, J. Phys. D: Appl. Phys.21,975 (1988).

    Article  CAS  Google Scholar 

  17. M. K. El-Adawi and S. A. Shalaby, J. Appl. Phys.63, 2212(1988).

    Article  Google Scholar 

  18. T. T. Kodas, T. H. Baum and P. B. Comita, J. Appl. Phys.61, 2749 (1987).

    Article  CAS  Google Scholar 

  19. S. D. Allen, J. A. Goldstone, J. P. Stone and R. Y. Jan, J. Appl. Phys.59, 1653 (1986).

    Article  CAS  Google Scholar 

  20. N. S. Gluck, Z. Ying, C. E. Bartosch and W. Ho, J. Chem Phys.86, 4957 (1987).

    Article  CAS  Google Scholar 

  21. G. H. Cheesman and H. J. Emeleus, J. Chem. Soc. 2847 (1932).

  22. J. Haigh,J. Mater. Sci.18, 1072 (1983).

    Article  CAS  Google Scholar 

  23. P. Balk, H. Heinecke, N. Putz, C. Plass and H. Luth, J. Vac. Sci. Technol.A4, 711 (1986).

    Google Scholar 

  24. D. H. Reep and S. K. Ghandi, J. Electrochem. Soc.130, 675(1983).

    Article  CAS  Google Scholar 

  25. N. Putz, E. Veuhoff, H. Heinecke, M. Heyen, H. Luth and P. Balk, J. Vac. Sci. Technol.B3, 671 (1985).

    Google Scholar 

  26. K. Tamara, J. Phys. Chem.59, 777 (1955).

    Article  Google Scholar 

  27. S. Horiguchi, K. Kimura, K. Kamon, M. Mashita, M. Shimazu, M. Mihara and M. Ishii, Jpn. J. Appl. Phys.25, L979(1986).

    Article  CAS  Google Scholar 

  28. N. Putz, H. Heinecke, M. Heyen, P. Balk, M. Weyers and H.Luth, J. Cryst. Growth74, 292 (1986).

    Article  Google Scholar 

  29. M. Mashita, S. Horiguchi, M. Shimazu, K. Kamon, M. Mihara and M. Ishii, J. Cryst. Growth77, 194 (1986).

    Article  CAS  Google Scholar 

  30. M. Yoshida, H. Watanabe and F. Uesugi, J. Electrochem. Soc.132, 677 (1985).

    Article  CAS  Google Scholar 

  31. D. P. Norton and P. K. Ajmera, Appl. Phys. Lett.53, 595(1988).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Norton, D.P., Ajmera, P.K. Ultraviolet light-driven epitaxial growth of gallium arsenide at reduced substrate temperatures. J. Electron. Mater. 19, 367–374 (1990). https://doi.org/10.1007/BF02651299

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02651299

Key words

Navigation