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The recovery of molybdenum from leach solutions by reduction

  • Hydrometallurgy
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Abstract

The feasibility of reductive precipitation of molybdenum oxides for molybdenum recovery from hypochlorite leach solutions has been investigated. Hydrogen gas at elevated temperature and pressure and hydrazine hydrate were used as reductants. The results are interpreted in terms of the behavior of mixed valent molybdenum polyanions.

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References

  1. I.H. Warren, A. Ismay, and J. King:Can. Metall. Q., 1977, vol. 16 (1–4 Metall. Soc. CIM: Annu. vol. featuring Molybdenum), pp. 11–20.

    CAS  Google Scholar 

  2. I.H. Warren and D.M. Mounsey: Chemetics International Company, a Div. of C-I-L Inc., 1818 Cornwall Avenue, Vancouver, BC, Canada, V6J 1C7, unpublished research, 1980.

  3. R.E. Lindstrom and B.J. Scheiner:Rep. Invest.-U.S. Bur. Mines, RI 7802, 1974, p. 12.

  4. D.D. Fischer, D.J. Bauer, and R.E. Lindstrom:Rep. Invest.-U.S. Bur. Mines, RI 8088, 1975, p. 12.

  5. D.S. Barr, R.E. Lindstrom, and D.L. Hendrix:Int. J. Miner. Process., 1975, vol. 2, pp. 303–20.

    Article  CAS  Google Scholar 

  6. D.S. Barr, B.J. Scheiner, and J.L. Hendrix:Int. J. Miner. Process., 1977, vol. 4, pp. 83–88.

    Article  CAS  Google Scholar 

  7. B.J. Scheiner, R.E. Lindstrom, and D.L. Pool:Rep. Invest.-U.S. Bur. Mines, RI 8145, 1976, p. 12.

    Google Scholar 

  8. B.J. Scheiner, D.L. Pool, R.E. Lindstrom, and G.E. McCleland:Rep. Invest.-U.S. Bur. Mines, RI 8357, 1979, p. 13.

  9. Z.M. Lyapina and A.N. Zelikmann:Tsvetn. Met., 1959, pp. 93–99.

  10. A.N. Zelikman and Z.M. Lyapina:Tsvetn. Met., 1960, pp. 119–25.

  11. S.I. Sobol:Sb. Nauchn. Tr.-Gos. Nauchno.-Issled. Inst. Tsvetn. Met., 1961, vol. 18, pp. 414–37.

    Google Scholar 

  12. A.N. Zelikman and Z. M. Lyapina:Planseeber. Polvermetall., 1961, vol. 8, pp. 148–55.

    CAS  Google Scholar 

  13. R. Wagenmann and O. Siebenhuener: East German patent 57,595 (1967), p. 2.

  14. W. Kunda and B. Rudyk:Planseeber. Pulvermetall., 1965, vol. 13, pp. 157–77.

    CAS  Google Scholar 

  15. M.E. Messner and S.R. Zimmerly: U.S. Patent 3,376,104 (1968), p. 6.

  16. M. Pourbaix:Atlas of Electrochemical Equilibria in Aqueous Solutions, 2nd English ed., National Association of Corrosion Engineers, Houston, TX, 1974, pp. 272–79.

    Google Scholar 

  17. M. Ardon and A. Pernick:J. Less-Common Met., 1977, vol. 54, pp. 233–41.

    Article  CAS  Google Scholar 

  18. Ya. R. Katsobashvili:Russ. J. Inorg. Chem., 1960, vol. 5, pp. 1295–98.

    Google Scholar 

  19. P. Souchay, M. Cadiot, and B. Viossat:Bull. Soc. Chim. Fr., 1970, pp. 892–98.

  20. P. Souchay:C. R. Hebd. Seances Acad. Sci., Ser. C, 1966, vol. 262, pp. 1524–27.

    CAS  Google Scholar 

  21. G.W. Watt and D.D. Davies:J. Am. Chem. Soc., 1948, vol. 70, pp. 3751–52.

    Article  CAS  Google Scholar 

  22. S. Ostrowetsky and D. Brinon:C. R. Hebd. Seances Acad. Sci., Ser. C, 1966, vol. 263, pp. 406–09.

    CAS  Google Scholar 

  23. A.I. Vogel:A Text-Book of Quantitative Inorganic Analysis, Longman, Green, and Co., London, 1949, p. 447.

    Google Scholar 

  24. W.G. Palmer:Experimental Inorganic Chemistry, Cambridge University Press, Cambridge, 1954, pp. 407–08.

    Google Scholar 

  25. G. Charlot:L'Analyse Quantitative et les Reactions en Solution, 4th ed., Masson, Paris, 1957, p. 257.

    Google Scholar 

  26. R. Holtje and R. Geyer:Z. Anorg. Allg. Chem., 1941, vol. 246, pp. 258–74.

    Article  CAS  Google Scholar 

  27. K. Grasshof and H. Hahn:Z. Anal. Chem., 1962, vol. 186, pp. 132–47.

    Article  Google Scholar 

  28. J.P. Schwing:C.R. Hebd. Seances Acad. Sci., 1962, vol. 254, pp. 4018–20.

    CAS  Google Scholar 

  29. C.F. Baes and R.E. Messner:The Hydrolysis of Cations, John Wiley and Sons, New York, NY, 1976, pp. 253–57.

    Google Scholar 

  30. D.F. Clausen and J.H. Shroyer:Anal. Chem., 1948, vol. 20, pp. 925–26.

    Article  CAS  Google Scholar 

  31. S. Ostrowetsky:Bull. Soc. Chim. Fr., 1964, pp. 1003-35.

  32. W.F. Jakob and W. KozlowskiiRocz. Chem., 1929, vol. 9, pp. 667–75.

    CAS  Google Scholar 

  33. T. Huang and J.T. Spence:J. Phys. Chem., 1968, vol. 72, pp. 4198–202.

    Article  CAS  Google Scholar 

  34. H.C. Mishra and R.N.P. Sinha:India J. Chem., 1971, vol. 9, pp. 1300–01.

    CAS  Google Scholar 

  35. W.C.E. Higginson:Spec. Publ. Chem. Soc., 1957, vol. 10, pp. 95–112.

    Google Scholar 

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Warren, I.H., Reid, D.C. The recovery of molybdenum from leach solutions by reduction. Metall Trans B 13, 565–570 (1982). https://doi.org/10.1007/BF02650013

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