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Crystal multiplication in undercooled Cu + 2 Pct Sn alloy

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Abstract

The effects of undercooling (AT) from 10 to 175° on grain structure were observed in a Cu + 2 wt pct Sn alloy, in which grain refinement does not occur at large degrees of under-cooling. Quenching soon after recalescence retained transient grain structures not previ-ously reported in the literature. Crystal multiplication by dendrite fragmentation occur-red when undercooling below the liquidus lay in the range △T = 10 to 70°, and resulted in complete grain refinement in the range △T = 50 to 70°. Fragmentation affected primary, secondary and tertiary dendrite arms during and after recalescence. At △T = 70° a sharp transition occurred to a radiating fan-shaped structure of twin-related grains ori-ginating from a single point of nucleation, with no evidence of fragmentation. It is pro-posed that the transition results from a change in the free dendritic growth mode, the new shape being a wholly primary form without side-arms. The absence of fragmentation in this range (△T > 70°) suggests that self-buckling contributes to fragmentation in the other range (△T < 70°) and could be at least equal in importance to remelting.

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Formerly with the University of Queensland, Australia, and the National Research Council of Canada, Ottawa

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McLeod, A.J., Hogan, L.M. Crystal multiplication in undercooled Cu + 2 Pct Sn alloy. Metall Trans A 9, 987–998 (1978). https://doi.org/10.1007/BF02649844

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