Skip to main content
SpringerLink
Log in

Bainitelike transformations in some oxide ceramics

  • Published:
Metallurgical and Materials Transactions A Aims and scope Submit manuscript

Abstract

The authors show two examples of “bainitelike” transformations in some oxide ceramics. A bainitelike transformation means that a shear (martensitic) mechanism is controlled by, or together with, ionic diffusion in the lattice as well as the case of lower bainite in steel. The first example is a tetragonal-to-monoclinic transformation in ZrO2-Y2O3 ceramics, where the bainitelike transformation must be characterized by (1) the increase in concentration of oxygen vacancies caused by the substitution of Zr4+ ions by Y3+ ions, (2) a fairly high mobility of oxygen ions through their vacancies, and (3) the formation of clusters composed of oxygen vacancies and oxygen ions. The second case is an inverse spinel to corundum structural change observed in γ Fe2O3 to α Fe2O3, in which the bainitelike transformation may be explained by cooperative movements of oxygen and ferric ions, which are sandwiched between oxygen layers.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Z. Nishiyama:Martensitic Transformation: Application Series, Maruzen, Tokyo, 1974, pp. 29–68.

    Google Scholar 

  2. H.I. Aaronson and G.W. Lorimer:Scripta Metall., 1972, vol. 6, pp. 1091–94.

    Article  CAS  Google Scholar 

  3. G.K. Bansal and A.H. Heuer:Acta Metall., 1972, vol. 20, pp. 1281–89.

    Article  CAS  Google Scholar 

  4. M. Hayakawa, N. Kuntani, and M. Oka:Acta Metall., 1989, vol. 37, pp. 2223–28.

    Article  CAS  Google Scholar 

  5. G. Hägg:.ZPhys. Chem., 1935, vol. B29, pp. 95–103.

    Google Scholar 

  6. B.T.M. Wills and H.P. Rooksby:Proc. Phys. Soc, 1952, vol. B65, pp. 950–54.

    Google Scholar 

  7. J.D. Bemal, D.R. Dasgupta, and A.L. Mackay:Nature, 1957, vol. 180, pp. 645–47.

    Article  Google Scholar 

  8. S. Kachi, K. Momiyama, and S. Shimizu:J. Phys. Soc. Jpn., 1963, vol. 18, pp. 106–16.

    Article  Google Scholar 

  9. S. Kachi, N. Nakanishi, K. Kosuge, H. Hiramatsu, and M. Kiyama:Proc. Int. Conf. on Ferrites, University of Tokyo Press, Tokyo, 1970, pp. 141–43.

    Google Scholar 

  10. N. Nakanishi, T. Shigematsu, T. Sugimura, and H. Okinaka:Zirconia Ceramics, Uchidarokakuho, Tokyo, 1986, vol. 8, pp. 71–85.

    Google Scholar 

  11. H. Tsubakino: Himeji Institute of Technology, Himeji, Hyogo, private communication, 1992.

  12. M. Yashima: Ph.D. Thesis, Tokyo Institute of Technology, Tokyo, 1991, pp. 92-117.

  13. G.K. Bansal and A.H. Heuer:Acta Metall., 1974, vol. 22, pp. 409–17.

    Article  CAS  Google Scholar 

  14. K. Koto, H. Shulz, and R.A. Huggins:Solid State Ionics, 1980, vol. 1, pp. 355–65.

    Article  CAS  Google Scholar 

  15. A.K. Cheetham, B.E.F. Fender, and M.J. Cooper:J. Phys. C, 1971, vol. 4, pp. 3107–21.

    Article  CAS  Google Scholar 

  16. H. Tsubakino: Himeji Institute of Technology, Himeji, Hyogo, private communication, 1992.

  17. S. Iida:J. Phys. Soc. Jpn., 1957, vol. 12, pp. 222–33.

    Article  CAS  Google Scholar 

  18. G.D. Nicolls:Adv. Phys., 1955, vol. 4, pp. 113–90.

    Article  Google Scholar 

  19. J.W. Christian:Proc. R. Soc. London A, 1951, vol. A206, pp. 51–64.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Science, Konan University, Higashinada-Ku, 652, Kobe, Japan

    N. Nakanishi (Professors), T. Shigematsu (Professors), T. Furukawa (Postdoctoral Fellow) & N. Machida (Lecturer)

Authors
  1. N. Nakanishi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. Shigematsu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. Furukawa
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. Machida
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

This article is based on a presentation made at the Pacific Rim Conference on the “Roles of Shear and Diffusion in the Formation of Plate-Shaped Transformation Products,” held December 18-22, 1992, in Kona, Hawaii, under the auspices of ASM INTERNATIONAL’S Phase Transformations Committee.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nakanishi, N., Shigematsu, T., Furukawa, T. et al. Bainitelike transformations in some oxide ceramics. Metall Mater Trans A 25, 2647–2653 (1994). https://doi.org/10.1007/BF02649218

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02649218

Keywords

Search

Navigation