Abstract
The most recent and exciting development in permanent magnet research is the discovery of rare-earth nitrides and carbides with the 2:17- and l:12- type structures. Nitrogen and carbon enter the lattice interstitially, expanding the volume of the unit cell and leading to a drastic increase in the Curie temperature (up to 300 °C) and to dramatic changes in the magnetic anisotropy. Sm2Fe17N(C))x and Nd(Fe,T)12Nx now have large magnetic anisotropy fields exceeding 9 and 7 T, respectively. Large coercivities have already been obtained in mechanically alloyed powders, melt- spun ribbons, and Zn- bonded Sm2Fe17Nx magnets.
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D.B. de Mooij and K.H.J. Buschow,J. Less-Common Met., 142, 349(1988).
X.P. Zhong, R.J. Radwanski, F.R. de Boer, T.H. Jacobs, and K.H.J. Buschow,J. Magn. Magn. Mater., 86, 333 (1990).
X.C. Kon, R. Grössinger, T.H. Jacobs, and K.J.H. Buschow,J. Magn. Magn. Mater., 80, 1 (1990).
J.M.D. Coey and H. Sun,J. Magn. Magn. Mater., 87, L251 (1990).
Y.Z. Wang and G.C. Hadjipanayis,J. Appl. Phys., 70(10), 6009 (1991).
J.M.D. Coey, J.F. Lawler, Hong Sun, and J.E.M. Allan,J. Appl. Phys., 69, 3007 (1991).
R.B. Helmholdt and K.H.J. Buschow,J. Less-Common Met., 155, 15(1989).
M.W. Dirker, R.C. Thiel, LJ. de Jongh, T.H. Jacobs, and K.H.J. Buschow,J. Less-Common Met., 155, 339 (1989).
P.C.M. Gubbens, A.M. van de Kraan, T.H. Jacobs, and K.H.J. Buschow,J. Magn. Magn. Mater., 155, 339 (1989).
Y.Z. Wang and G.C. Hadjipanayis, “Magnetic Properties of R2Fe17Nx Compounds” Paper No. SP1, Sixth Int. Symp. on Magnetic Anisotropy and Coercivity in Rare-Earth-Transition Metal Alloys, Pittsburgh, Oct (1990).
J.M.D. Coey, H. Sun, and Y. Otani, “A New Family of Rare Earth Iron Nitrides,” Sixth Int. Symp. on Magnetic Anisotropy and Coercivity in Rare-Earth-Transition Metal Alloys, 36, Pittsburgh, Oct (1990).
K. Schnitzke, L. Schultz, J. Wecker, and M. Katter,Appl. Phys. Lett., 57, 2583(1990).
J.M.D. Coey and H. Sun,J. Magn. Magn. Mater., 87, L251 (1990).
M.Q. Huang, L.Y. Zhang, M.M. Ma, Y. Zheng, J.M. Elbicki, W.E. Wallace, and S.G. Sankar,J. Appl. Phys., 70(10), 6027 (1991).
J.M.D. Coey in “CEAM II Annual Report,” J.M.D. Coey, D. Givord, R. Harris, and R. Hanitsch, Eds. (1990).
K.H.J. Buschow, inFerromagnetic Materials, Vol 1, E.P. Wohlfarth, Ed., North-Holland, 389 (1980).
U.S. Ram and P. Gaunt,J. Appl. Phys., 54, 2872 (1983).
L.X. Liao, X. Chen, Z. Altounian, and R.H. Ryan,Appl. Phys. Lett., 60, 129 (1992).
Y. Wang and G.C. Hadjipanayis,J. Appl. Phys., 67,4954 (1990).
J.M.D. Coey, H. Sun, Y Otani, and D.P.F. Hurley,J. Magn. Magn. Mater., 98, 76(1991).
L. Schultz, K. Schnitzler, and J. Wecker,J. Appl. Phys. Lett., 56, 868 (1990).
S. Jaswal, W.B. Yelon, G.C. Hadjipanayis, Y.Z. Wang, and DJ. Sellmyer,Phys. Rev. Lett., 67,644 (1991).
W.E. Wallace, in Rare-Earth Intermetallics, Academic Press, New York, 14(1973).
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Hadjipanayis, G.C., Wang, Y.Z., Singleton, E.W. et al. Rare-earth nitrides and carbides: A new class of permanent magnet materials. JMEP 1, 193–203 (1992). https://doi.org/10.1007/BF02648617
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DOI: https://doi.org/10.1007/BF02648617