Skip to main content
Log in

The Ge- Li (Germanium-Lithium) system

  • Published:
Journal of Phase Equilibria

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Cited References

  1. H. Reiss, C.S. Fuller, and F.J. Morin, “Chemical Interactions Among Defects in Germanium and Silicon,≓Bell Syst. Tech. J., 35(3), 535 (1956). (Equi Diagram; Experimental)

    Google Scholar 

  2. R.N. Hall, “Variation of the Distribution Coefficient and Solid Solubility with Temperature,≓J. Phys. Chem. Solids, 3(1–2), 63–73 (1957). (Equi Diagram; Review)

    Article  ADS  Google Scholar 

  3. F.J. Morin and H. Reiss, “Precipitation of Li in Ge,≓J. Phys. Chem. Solids, 33–4, 196–209 (1957). (Equi Diagram; Review)

    Article  ADS  Google Scholar 

  4. E.M. Pell, “Solubility of Li in Ge,≓J. Phys. Chem. Solids, 31–2, 74–76(1957). (Equi Diagram; Experimental)

    Article  ADS  Google Scholar 

  5. H. Reiss and C.S. Fuller, “The Effect of Ion Pair and Ion Triplet Formation on the Solubility of Li in Ge. Effect of Ga and Zn, “J. Phys. Chem. Solids, 4(1–2), 58–67 (1958). (Equi Diagram, Review)

    Article  ADS  Google Scholar 

  6. F.A. Trumbore, “Solid Solubilities of Impurity Elements in Ge and Si,≓Bell Syst. Tech. J., 39(1), 205–233 (1960). (Equi Diagram; Review)

    Google Scholar 

  7. E.I. Gladyshevskii and P.I. Kripyakevich, ldCrystal Structure of Li15Ge4,≓Kristallographiya, 5(4), 574–576 (1960) in Russian; TR:Sov. Phys.-Cryst., 5(4), 549–551 (1961). (Equi Diagram, Crys Struc- ture; Experimental)

    Google Scholar 

  8. E.I. Gladyshevskii, G.I. Oleksiv, and P.I. Kripyakevich, “New Examples of the Structural Type Li22Pb5,≓Kristallografiya, 9(3), 338–341 (1964) in Russian; TR:Sov. Phys.-Cryst., 9(3), 269–271 (1964). (Crys Structure; Experimental)

    Google Scholar 

  9. G.I. Oleksiv, “Crystal Structures of Binary Compounds of Li with Sr, Ba, Al, Tl, Si, and Ge,≓Probl. Rozvitku Prirodn. Tochn. Nauk, Sb., 76-77 (1964) in Russian. (Crys Structure; Experimental)

  10. Q. Johnson, G.S. Smith, and D. Wood, “The Crystal Structure of Li15Ge4,≓Acta Crystallogr., 18, 131–132 (1965). (Equi Diagram, Crys Structure; Experimental)

    Article  Google Scholar 

  11. P.I. Fedorov and V.A. Molochko, “The Li-Ge System,≓Izv. Akad. Nauk SSSR, Neorg. Mater., 2(10), 1870–1871 (1966) in Rus- sian; TR:Inorg. Mater., 2(10), 1614–1616 (1966). (Equi Diagram; Experimental)

    Google Scholar 

  12. E. Menges, V. Hopf, H. SchÄfer, and A. Weiss, “The Crystal Structure of LiGe—A New Three-Dimensional Unit of Group IV Elements,≓Z. Naturforsch. B, 24B(10), 1351–1352(1969) in German. (Equi Diagram, Crys Structure; Experimental)

    Google Scholar 

  13. V. Hopf, H. SchÄfer, and A. Weiss, “The Crystal Structure of Li9Ge4,≓Z. Naturforsch. B, 25B(6),653 (1970) in German. (Equi Dia- gram, Crys Structure; Experimental)

    Google Scholar 

  14. G.H.R. Kegel, R.J. Laramee, and B.D. Bhardwaj, “The Free En- ergy of Mixing in the Li-Ge Binary System,≓J. Electrochem. Soc., 778(10), 1662–1665(1971). (Equi Diagram, Experimental)

    Article  Google Scholar 

  15. V. Hopf, W. Müller, and H. SchÄfer, “The Structure of Li7Ge2,≓Z Naturforsch. B, 27B(10), 1157–1160(1972) in German. (Equi Dia- gram, Crys Structure; Experimental)

    Google Scholar 

  16. P.F. Adams, P. Hubberstey, and R.J. Pulham, “Review of the Solubility of Non-Metals in Liquid Li,≓J. Less-Common Met., 42(1), 1–11 (1975). (Equi Diagram; Review)

    Article  Google Scholar 

  17. U. Frank and W. Müller, “Li11Ge6, A Phase with Isolated Planar Five-Membered Ge-Rings,≓Z. Naturforsch. B, 30B(5–6), 313–315 (1975) in German. (Equi Diagram, Crys Structure; Experimental)

    Google Scholar 

  18. J.A. Morrison and R.J. Lagow, “Chemistry of Polylithiated Species: Reactions of Polylithiated Silanes and Germanes,≓Inor- ganic Chem., 76(11), 2972–2974 (1977). (Experimental)

    Article  Google Scholar 

  19. A.D. Dadd and P. Hubberstey, “Solubilities of Si and Ge in Liq- uid Li,≓J. Chem. Soc. Faraday Trans. I, 77(8), 1865–1870 (1981). (Equi Diagram; Experimental; #)

    Article  Google Scholar 

  20. P. Hubberstey, R.J. Pulham, and A.E. Thunder, Unpublished Data Quotedby [81Dad] (1981). (Equi Diagram; Experimental)

  21. A. Grüttner, R. Nesper, and H.G. von Schnering, “New Phases in the Li-Ge System: Li7Ge12, Li12Ge7, and Li14Ge6,≓Acta Crystal- logr. A, 37(Suppl.), C-161 (1981). (Equi Diagram, Crys Structure; Experimental)

    Google Scholar 

  22. A. Grüttner, R. Nesper, and H.G. von Schnering, “Novel Me- tastable Ge Modifications: Allo-Ge and 4H-Ge from Li7Ge12,≓Angew. Chem., 94(12),933 (1982)in German; TR:Angew. Chem. Int. Ed. Engl, 27(12), 912–913 (1982). (Equi Diagram, Crys Structure; Experimental)

    Article  Google Scholar 

  23. P. Hubberstey, A.T. Dadd, and P.G. Roberts, “Solubilities of Non-Metals in Liquid Li—A Review,≓ inMaterial Behavior and Physical Chemistry in Liquid Metal Systems, H.U. Borgstedt, Ed., Plenum Press, New York, 445–453 (1982). (Equi Diagram; Review)

    Google Scholar 

  24. M.R. St. John, A.J. Furgala, and A.F. Sammells, “Thermody- namic Studies of Li-Ge Alloys: Application to Negative Electrodes for Molten Salt Batteries,≓J. Electrochem. Soc., 129(2), 246–250 (1982). (Equi Diagram, Crys Structure; Thermo; Experimental)

    Article  Google Scholar 

  25. B.P. Alblas, C. van der Marel, W. Geertsma, J.A. Meijer, A.B. van Oosten, J. Dijkstra, P.C. Stein, and W. vander Lugt, “Experimen- tal Results for Liquid Alkali—Group IV Alloys,≓J. Non-Cryst. Sol- ids, 61-62, 201–206 (1984). (Thermo; Experimental)

    Article  ADS  Google Scholar 

  26. I.M. Kotina, V.V. Kuryatkov, G.N. Mosina, S.R. Novikov, and L.M. Sorokin, “Formation of a New Phase During Precipitation of a Supersaturated Solid Solution of Li in Ge,≓Fiz Tverd. Tela Lenin-grad,26(2), 436–440 (1984) in Russian; TR:Soviet. Phys.—Solid State, 26(2),259–261 (1984). (Equi Diagram; Experimental)

    Google Scholar 

  27. R. Nesper, J. Curda, and H.G. von Schnering, “Li8MgSi6, A Novel Zintl Compound Containing Quasi-Aromatic Si5 Rings,≓J. Solid State Chem., 62(2), 199–206 (1986). (Equi Diagram, Crys Structure; Experimental)

    Article  ADS  Google Scholar 

  28. J. Evens, G. Oehlinger, G. Sextl, and H.-O. Becker, “High- Pressure LiGe with Layers Containing Two- and Four-Coordinate Ge Atoms,≓Angew. Chem., 99(1), 69–71 (1987) in German; TR:Angew. Chem. Int. Ed. Engl., 26(1), 76–78 (1987). (Equi Diagram, Crys Struc- ture, Pressure; Experimental)

    Article  Google Scholar 

  29. P. Sherwood and R. Hoffmann, “Ge-Ge Bonding in the High- Pressure Modification of LiGe: A Near-Zintl Phase,≓J. Am. Chem. Soc., 112(8), 2881–2886 (1990). (Crys Structure, Pressure; Theory) $

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

This work was supported by ASM International. Literature searched through 1992. Dr. Pelton is the Alloy Phase Diagram Program Category Co-Editor for Binary Alkali Systems.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sangster, J., Pelton, A.D. The Ge- Li (Germanium-Lithium) system. JPE 18, 289–294 (1997). https://doi.org/10.1007/BF02647856

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02647856

Keywords

Navigation