Skip to main content
Log in

analytical expressions for the activity of the solute in binary dilute solutions in terms of associated solution model parameters

  • Published:
Metallurgical Transactions A Aims and scope Submit manuscript

Abstract

Simple analytical expressions have been derived to express the activity of the solute in binary dilute solutions in terms of the Associated Solution Model (ASM) parameters. The activity coefficient of the solute at infinite dilution and the first and second order Wagner’s self-interaction parameters are, then, given as a function of ASM parameters for some simple cases.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. C. Sharma and Y. A. Chang:Metall. Trans. B, 1979, vol. 10B, pp. 103–08.

    CAS  Google Scholar 

  2. R.C. Sharma and Y. A. Chang:Metall. Trans. B, 1980, vol. llB, pp. 139–46.

    Google Scholar 

  3. Y.-Y. Chuang, K.-C. Hsieh, and Y. A. Chang:Metall. Trans. B, 1985, vol. 16B, pp. 277–85.

    CAS  Google Scholar 

  4. R. C. Sharma and Y. A. Chang:Zeit. Metalkunde, 1979, vol. 70, pp. 104–08.

    CAS  Google Scholar 

  5. R. C. Sharma and Y. A. Chang:Metall. Trans. B, 1980, vol. llB, pp. 575–80.

    Google Scholar 

  6. A. S. Jordan:Metall. Trans., 1970, vol. 1, pp. 239–49.

    CAS  Google Scholar 

  7. T. Tung, L. Golonka, and R. F. Brebrick:J. Electrochem. Soc., 1981, vol. 128, pp. 1601–12.

    Article  CAS  Google Scholar 

  8. J. D. Kelley, B.G. Martin, F. R. Szofran, and S.L. Lehoczky:J. Electrochem. Soc, 1982, vol. 129, pp. 2360–65.

    Article  CAS  Google Scholar 

  9. S. Szapiro:J. Electron. Mater., 1976, vol. 5, pp. 223–47.

    CAS  Google Scholar 

  10. K.-C. Hsieh, M.S. Wei, and Y. A. Chang:Z. Metalkunde, 1983, vol. 74, pp. 330–37.

    CAS  Google Scholar 

  11. R. F. Brebrick, C. H. Su, and P. K. Liao:Semicond. Semimetals, R. K. Willardson and A.C. Beer, eds., 1983, vol. 19, pp. 171-253.

  12. R. Schmid:Metall. Trans. B, 1983, vol. 14B, pp. 473–81.

    CAS  Google Scholar 

  13. A. Laugier:Rev. Phy. Appl., 1973, vol. 8, pp. 259–70.

    CAS  Google Scholar 

  14. A. Laugier, J. Cadoz, M. Faure, and M. Moulin:J. Cryst. Growth, 1974, vol. 21, pp. 235–42.

    Article  CAS  Google Scholar 

  15. K. Osamura and Y. Murakami:J. Phys. Chem. Solids, 1975, vol. 36, pp. 931–37.

    Article  CAS  Google Scholar 

  16. A. S. Jordan:Metall. Trans. B, 1976, vol. 7B, pp. 191–202.

    CAS  Google Scholar 

  17. S. Szapiro, N. Tamari, and H. Shtrikman:J. Electron. Mater., 1981, vol. 10, pp. 501–16.

    CAS  Google Scholar 

  18. R. Schmid and Y. A. Chang:CALPHAD, 1985, vol. 9, pp. 363–82.

    Article  CAS  Google Scholar 

  19. C. Wagner:Thermodynamics of Alloys, Addison-Wesley, Reading, MA, 1952, pp. 47–53.

    Google Scholar 

  20. C. H. P. Lupis:Chemical Thermodynamics of Materials, North- Holland, New York, NY, 1983, pp. 170–76.

    Google Scholar 

  21. Y.-Y. Chuang, R. Schmid, and Y. A. Chang:Metall. Trans. A, 1984, vol. 15A, pp. 1921–30.

    CAS  Google Scholar 

  22. I. Prigogine and R. Defay:Chemical Thermodynamics, Longmans Green and Co., London, 1965, pp. 410–11.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sharma, R.C. analytical expressions for the activity of the solute in binary dilute solutions in terms of associated solution model parameters. Metall Trans A 18, 1641–1644 (1987). https://doi.org/10.1007/BF02646147

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02646147

Keywords

Navigation