Skip to main content
SpringerLink
Log in

thermodynamic properties of liquid Ag-Si alloys

  • Published:
Metallurgical transactions Aims and scope Submit manuscript

Abstract

The thermodynamic properties of silicon in liquid Ag-Si alloys in the range of 1100 to 1325°C have been measured by an electrochemical cell employing silica-saturated lithium silicate as the electrolyte. The range of composition studied is 0.015 <x Si < 0.29. For the change in standard state from pure liquid silicon to silicon at infinite dilution with the composition in atom fraction: Si(I) = Si (inf. dil.): △G° = 5,000 + 5.47T, (J/g-atom) The results of the study are in good agreement with the measurements on the phase diagram by Hager.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. Chipman and R. Baschwitz:Trans. TMS-AIME, 1963, vol. 227, p. 473.

    CAS  Google Scholar 

  2. J. P. Hager:Trans. TMS-AIME, 1963, vol. 227, p. 1000.

    CAS  Google Scholar 

  3. T. J. O’Keefe: Thesis, Univ. of Missouri, 1965 (cited by Ref. 5).

  4. A. Vermandé, J. Ansara and P. Desré ;Rev. Int. Hautes Temper et Refract., 1970, vol. 7, p. 39.

    Google Scholar 

  5. V.S. Robinson and S.K. Tarby:Met. Trans. 1971, vol. 2, p. 1347.

    Article  CAS  Google Scholar 

  6. J. S. D’Entremont and J. Chipman:J.Phys. Chem., 1963, vol. 67, p. 499.

    Article  Google Scholar 

  7. G. Smith and J. Taylor:J. Iron SteelInst., 1964, vol. 202, p. 577.

    CAS  Google Scholar 

  8. E. T. Turkdogan and P. Grieveson:Trans. TMS-AIME, 1963, vol. 227, p. 1143.

    CAS  Google Scholar 

  9. K. Schwerdtfeger and H. J. Engell ;Arch. Eisenhuettenw., 1964, vol. 35, pp. 535–40.

    Google Scholar 

  10. E. M. Levin, H. F. McMurdie and F. P. Hall: Phase Diagrams for Ceramists, American Ceramic Soc, Columbus University, 1956.

    Google Scholar 

  11. R. Hultgren, R. L. Orr, P.D. Anderson and K. K. Kelley:Selected Values of Thermodynamic Properties of Metals and Alloys, 1963, John Wiley & Sons, Inc., and subsequent additions.

  12. R. H. Tupkary:Ind. Jnl. of Technology, 1967, vol. 5, pp. 14–16.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Nagoya University, Nagoya-shi, Japan

    Hiroshi Sakao (Professor, Faculty of Engineering)

  2. Mass. Inst. Technology, 02139, Cambridge, Mass.

    John F. Elliott (Fellow of TMS and of ASM, Professor of Metallurgy)

Authors
  1. Hiroshi Sakao
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. John F. Elliott
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Member of AIME; Visiting Scientist, Mass.(1969)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sakao, H., Elliott, J.F. thermodynamic properties of liquid Ag-Si alloys. Metall Trans 5, 2063–2067 (1974). https://doi.org/10.1007/BF02644499

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02644499

Keywords

Search

Navigation