Skip to main content

Molybdenum metal by the aluminothermic reduction of calcium molybdate

Abstract

This investigation deals with a process for extracting molybdenum metal in well consoli-dated form and in good yield from calcium molybdate, by open aluminothermic reduction. Aluminothermic molybdenum has been further processed both by electron-beam melting and by molten salt electrorefining for the removal of aluminum. The final metal compares very favorably with commercial molybdenum obtainable by other routes.

This is a preview of subscription content, access via your institution.

References

  1. H. Goldschmidt:Annalen der Chemie, Justus Liebigs, 1898, vol. 301, pp. 19–28.

    CAS  Google Scholar 

  2. G. L. Miller:Iron Steel (London), 1964, vol. 37, pp. 174–78.

    CAS  Google Scholar 

  3. Georg Brouer:Handbook of Preparative Inorganic Chemistry, Vol. 2, p. 1401, Academic Press, New York, 1956.

    Google Scholar 

  4. C. K. Gupta and P. K. Jena:J. Less Common Metals, 1968, vol. 14, p. 148.

    Article  CAS  Google Scholar 

  5. F. A. Schmidt, R. M. Bergman, O. N. Carlson, and H. A. Wilhelm:J. Metals, August 1971, vol. 23, pp. 38–44.

    CAS  Google Scholar 

  6. B. I. Khlebnikov and A. P. Nadol’skii:Tr. Irkutsk. Politekh. Inst., 1969, no. 47, pp. 20–26,Chem. Abstr., 1970, vol. 73, p. 47666U.

  7. T. K. Mukherjee and C. K. Gupta:J. Less Common Metals, 1972, vol. 27, pp. 251–54.

    Article  CAS  Google Scholar 

  8. G. R. Kamat and C. K. Gupta:Met. Trans., 1971, vol. 2, pp. 2817–23.

    CAS  Google Scholar 

  9. R. E. Cumings, F. R. Cattoir, and T. A. Sullivan:U.S. Bur. Mines Rept. Invst. No. 6850, 1966.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Mehra, O.K., Bose, D.K. & Gupta, C.K. Molybdenum metal by the aluminothermic reduction of calcium molybdate. Metall Mater Trans B 4, 691–694 (1973). https://doi.org/10.1007/BF02643076

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02643076

Keywords

  • Molybdenum
  • Molten Salt
  • Preheat Temperature
  • Slide Valve
  • Metal Separation