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The effect of carbide and nitride additions on the heterogeneous nucleation behavior of liquid iron

An Erratum to this article was published on 01 October 1970


A systematic study of carbide and nitride additions on the heterogeneous nucleation behavior of supercooled liquid iron was undertaken. It was found that titanium nitride and titanium carbide were very effective in promoting heterogeneous nucleation. These compounds were followed by silicon carbide, zirconium nitride, zirconium carbide, and tungsten carbide in decreasing order of effectiveness. The degree of potency of the nucleation catalysts is explained on the basis of the disregistry between the lattice parameters of the substrate and the nucleating phase. Through the inclusion of planar terms the Turnbull-Vonnegut “linear” disregistry equation was modified to more accurately describe the crystallographic relationship at the interface during heterogeneous nucleation.

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  1. L.M. Hogan and G. L. F. Powell:J. Austral. Inst. Metals, 1966, vol. 11, p. 235.

    CAS  Google Scholar 

  2. A. Walton:International Science and Technology, Dec. 1966, p. 28.

  3. K. A. Jackson,Ind. Eng. Chem., 1965, vol. 57, p. 28.

    Article  CAS  Google Scholar 

  4. G. A. Chadwick:Metals and Materials, 1969, vol. 3, no. 3, p. 77.

    CAS  Google Scholar 

  5. B. E. Sundquist and L.F. Mondolfo:Trans. TMS-AIME, 1961, vol. 221, p. 607.

    CAS  Google Scholar 

  6. G. M. Pound:Liquid Metals and Solidification, p. 87, ASM, 1958.

  7. W. A. Tiller and T. Takahashi:Acta Met., 1969, vol. 17, p. 483.

    Article  CAS  Google Scholar 

  8. D. Tumbull and R. Vonnegut:Ind. Eng. Chem., 1952, vol. 44, p. 1292.

    Article  Google Scholar 

  9. P. J. Bradshaw, M. E. Gasper, and S. Pearson:J. Inst. Metals, 1958, vol. 87, p. 15.

    CAS  Google Scholar 

  10. B.E. Sundquist and L. F. Mondolfo:Trans. TMS-AIME, 1961, vol. 221, p. 157.

    CAS  Google Scholar 

  11. J. A. Reynolds and C. R. Tottle:J. Inst. Metals, 1951, vol. 80, p. 1328.

    Google Scholar 

  12. M. E. Glicksman and W. J. Childs:Acta Met, 1962, vol. 10, p. 925.

    Article  CAS  Google Scholar 

  13. G. K. Turnbull, D. M. Patton, G. W. Form, and J. F. Wallace:Trans. Am. Foundrymen’s Soc, 1960, vol. 69, p. 792.

    Google Scholar 

  14. N. Church, P. Wieser, and J. F. Wallace:Mod. Castings, 1966, p. 129.

  15. J. F. Wallace:Proc. Electric Furnace Conf., 1962, p. 125.

  16. G. K. Turnbull, G. W. Form, and J. F. Wallace: 1962, U. S. Patent No. 3,308,515.

  17. J. E Wallace:J. Metals, 1963, p. 372.

  18. P. B. Crosley, A. W. Douglas, and L. F. Mondolfo:Iron Steel Institute, Publication 110,1967, p. 10.

  19. A. Goldsmith, T. E. Waterman, and H. J. Hirschhorn:Handbook of Thermophysical Properties of Solid Materials, 1961, vol. 4.

  20. F. Kralik and P. Seb.:Kovove Materialy, 1965, vol. 3, p. 106.

    CAS  Google Scholar 

  21. A. Hoffmann:Arch. Eisenhuttenw., 1967, vol. 38, p. 785.

    CAS  Google Scholar 

  22. A. Taylor and B. J. Kagel: Crystallographic Data on Metal and Alloy Structures, Dover, New York, 1963.

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Bramfitt, B.L. The effect of carbide and nitride additions on the heterogeneous nucleation behavior of liquid iron. Metall Mater Trans B 1, 1987–1995 (1970).

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  • Carbide
  • Tungsten Carbide
  • Heterogeneous Nucleation
  • Titanium Carbide
  • Liquid Iron