Abstract
An earlier paper on the mechanism of localized corrosion of 7075 alloy plate in 3.5 pct NaCl solution showed that pitting of an anodic zone in the vicinity of grain boundaries caused intergranular corrosion of 7075-T651 (peak aged condition). It also showed that overaging to the T7351 temper reduced the difference between pitting potentials of the grain boundaries and grain interiors so that intergranular corrosion could not be sustained. This paper shows that certain changes in the environment strongly affect the difference between pitting potentials of the grain interior and the anodic grain boundary of 7075-T7351. Consequently, the susceptibility for intergranular corrosion is substantially greater in certain environments. Nitrates are most detrimental. The effects of sulfates and pH in chloride + nitrate solutions were relatively small.
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Maitra, S., English, G.C. Environmental factors affecting localized corrosion of 7075-t7351 aluminum alloy plate. Metall Trans A 13, 161–166 (1982). https://doi.org/10.1007/BF02642428
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DOI: https://doi.org/10.1007/BF02642428