Skip to main content
Log in

Kinetics of diffusion in the Nb-Al system

  • Published:
Metallurgical Transactions Aims and scope Submit manuscript

Abstract

Diffusion kinetics were studied by varying the time and temperature (800° to 1300°C) of dipping solid niobium into molten aluminum. It was found by X-ray diffraction analysis that only the Al3Nb phase forms at the surface of the niobium specimen and that the thickness of this layer for a given dip temperature varies parabolically with time. The activation energy and the preexponential factor of the diffusion parameter, (δD) were found to be 36.5 ∓ 0.45 kcal per mole and 2.0 ∓ 0.34 sq cm per sec, respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. W. B. Hall and J. W. Graham:AIME Conf., 1961, vol. 18, p. 789.

    Google Scholar 

  2. R. A. Jefferys and J. W. Cadd:AIME Conf., 1961, vol. 18, p. 801.

    Google Scholar 

  3. E. N. Bamberger, R. G. Frank, L. Luft, and E. D. Sayre:AIME Conf., 1961, vol. 18, p. 773.

    Google Scholar 

  4. R.G. Carlson:AIME Conf., 1960, vol. 10, p. 119.

    Google Scholar 

  5. B. Lustman and R. F. Mehl:AIME Trans., 1942, vol. 147, p. 369.

    Google Scholar 

  6. V. I. Borisov, V. M. Golikov, and G. N. Dubinin:Phys. Metals Metallog., 1965, vol. 20, p. 63.

    Google Scholar 

  7. Ya. I. Frenkel and M. I. Sergeev:Zh. Eksp. Teor. Fiz., 1939, vol. 9, p. 189.

    Google Scholar 

  8. B. I. Boltaks:Diffusion in Semiconductors, p. 67, Academic Press, 1963.

  9. C. E. Lundin and A. S. Tamamoto:Trans. TMS-AIME, 1966, vol. 236, p. 863.

    Google Scholar 

  10. O. Kubaschewski and B. E. Hopkins:Oxidation of Metals and Alloys, p. 2, Academic Press, 1962.

  11. C. Wagner:Acta Met, 1969, vol. 17, p. 99.

    Article  Google Scholar 

  12. T. G. Stoebe, R. D. Gulliver II, T. O. Ogurtani, and R. A. Huggins:Acta Met., 1965, vol. 13, p. 701.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Oğurtani, T. Kinetics of diffusion in the Nb-Al system. Metall Trans 3, 425–429 (1972). https://doi.org/10.1007/BF02642046

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02642046

Keywords

Navigation