Summary
Solubility data have been presented for monostearin, monopalmitin, and monoglycerides of triple-pressed stearic acid and hydrogenated lard in cotton-seed oil. Monoglyceride precipitated from solution by quick chilling became less soluble after tempering 18 hrs. at 45°C. Decreased solubility was related to increased crystallinity as determined by X-ray diffraction. Solubility data thus confirmed conclusions previously reported that tempering operates to improve global spread primarily through recrystallization which is now shown to involve converting precipitates of low degree of molecular order into more perfect crystals.
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References
Bailey, A. E., “Melting and Solidification of Fats,” p. 304, New York, Interscience Publishers Inc., 1950.
Bunn, C. W., “Chemical Crystallography,” p. 367, Oxford (1946).
Fulton, N. D., Lutton, E. S., and Wille, R. L., J. Am. Oil Chemists' Soc.,31, 98–103 (1954).
Harbury, L., J. Phys. Chem.,50, 190–199 (1946).
Hellman, N. N., Zobel, H. F., and Senti, F. R., J. Am. Oil Chemists' Soc.,32, 110–114 (1955).
Hofgaard, K., “Dilatometriske Fedstof-Undersogelser,” J. Jorgensen and Co., Copenhagen, 1938.
Hulett, G. A., in “Colloid Chemistry” edited by J. Alexander, vol. 1, p. 637, New York, Chemical Catalog Co., 1926.
Jensen, H. R., “Chemistry, Flavoring, and Manufacture of Chocolate Confectionery and Cocoa,” p. 214–8, Blakiston, Philadelphia, 1931.
Lancaster, E. B.,et al., J. Am. Oil Chemists' Soc.,32, 9–13 (1955).
Lutton, E. S., J. Am. Oil Chemists' Soc.,27, 276–81 (1950).
Malkin, T., and el Shurbagy, M. R., J. Chem. Soc., 1628–1634 (1936).
Malkin, T., in “Progress in the Chemistry of Fats and Other Lipids,” vol. 2, p. 1–50, New York, Academic Press Inc., 1954.
Ward, T. L., Gros, A. T., and Feuge, R. O., presented at American Oil Chemists’' Society meeting, San Antonio, Tex., Apr. 12–14, 1954.
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Hellman, N.N., Zobel, H.F. & Senti, F.R. Solubility of monoglycerides in oil and its relation to the production of global edible spread. J Am Oil Chem Soc 32, 489–492 (1955). https://doi.org/10.1007/BF02639947
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DOI: https://doi.org/10.1007/BF02639947