Skip to main content
Log in

Effect of catalytic treatment with sodium methylate on glycerine composition and properties of lard and tallow

  • Published:
Journal of the American Oil Chemists Society

Summary

Treatment of lard with sodium methylate did not affect fatty acid composition nor the usual chemical constants and melting points. The glyceride composition however was altered considerably and showed close agreement with values calculated for random distribution. This change in glyceride composition was accompanied by significant changes in physical character as shown by consistency numbers, dilatometric and micropenetration measurements, and cooling curves.

Beef tallow remained almost unaffected by the sodium methylate treatment. The glyceride composition before and after treatment as determined by Kartha's method agreed well with values calculated for random distribution. Only the cooling curves indicated any change induced by the treatment.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Bailey, A. E., U. S. Patent Applications 319,130 (1940); 478,078 (1943).

  2. Bailey, A. E., “Industrial Oil and Fat Products”, Interscience Publishers, New York, 2nd ed., page 682 (1951).

    Google Scholar 

  3. Desnuelle, P., and Naudet, M., Bull. soc. chim. France, 90–94 (1946).

  4. Eckey, E. W., Ind. Eng. Chem.,40, 1183–1190 (1948).

    Article  CAS  Google Scholar 

  5. Eckey, E. W., U. S. Patents 2,378,005 (1945); 2,378,006 (1945); 2,378,007 (1945); and 2,442,531 (1948).

  6. Feuge, R. O., and Bailey, A. E., Oil and Soap,21, 78–84 (1944).

    Article  Google Scholar 

  7. Fulton, N. D., Lutton, E. S., and Wille, R. L., J. Am. Oil Chemists' Soc.,31, 98–103 (1954).

    Article  CAS  Google Scholar 

  8. Gooding, C. M., U. S. Patent 2,309,949 (1943).

  9. Grün, A., Z. Angew Chem.,38, 827 (1925).

    Google Scholar 

  10. Harrington, B. S., Crist, F. B., Kiess, A. A., and Jacob, W. A., Oil and Soap,22, 29–30 (1945).

    Article  Google Scholar 

  11. Herb, S. F., and Riemenschneider, R. W., Anal. Chem.,25, 953–955 (1953).

    Article  CAS  Google Scholar 

  12. Hoerr, C. W., and Waugh, D. F., J. Am. Oil Chemists' Soc.,32, 37–41 (1955).

    CAS  Google Scholar 

  13. Kartha, A. R. S., J. Am. Oil Chemists' Soc.,30, 280–282 (1953).

    CAS  Google Scholar 

  14. Luddy, F. E., Fertsch, G. R., and Riemenschneider, R. W., J. Am. Oil Chemists' Soc.,31, 266–268 (1954).

    CAS  Google Scholar 

  15. Naudet, M., and Desnuelle, P. Bull. soc. chim. France, 323–325 (1947).

  16. Normann, W., Ger. Patent 417,215 (1925).

  17. Norris, F. A., and Mattil, K. F., Oil and Soap,23, 289–291 (1946).

    Article  CAS  Google Scholar 

  18. Norris, F. A., and Mattil, K. F., J. Am. Oil Chemists' Soc.,24, 274–275 (1947).

    CAS  Google Scholar 

  19. Pohle, W. D. and Mehlenbacher, V. C., J. Am. Oil Chemists' Soc.,27, 54–56 (1950).

    Article  CAS  Google Scholar 

  20. Quimby, O. T., Wille, R. L., and Lutton, E. S., J. Am. Oil Chemists' Soc.,30, 186–190 (1953).

    CAS  Google Scholar 

  21. Riemenschneider, R. W., Luddy, F. E., Swain, M. L., and Ault, W. C., Oil and Soap,23, 276–282 (1946).

    Article  CAS  Google Scholar 

  22. Schroeder, W. F., Transactions, American Association of Cereal Chemists, Vol. X, p. 141–148 (1952).

    Google Scholar 

  23. Vander Wal, R. J., and Van Akkeren, L. A. U. S. Patent 2,571,315 (1951).

  24. Van Loon, C., British Patent 249,916 (1924).

  25. Van Loon, C., U. S. Patents 1,744,596 (1930); 1,873,513 (1932).

Download references

Author information

Authors and Affiliations

Authors

Additional information

A laboratory of the Eastern Utilization Research Branch, Agricultural Research Service, U. S. Department of Agriculture.

About this article

Cite this article

Luddy, F.E., Morris, S.G., Magidman, P. et al. Effect of catalytic treatment with sodium methylate on glycerine composition and properties of lard and tallow. J Am Oil Chem Soc 32, 522–525 (1955). https://doi.org/10.1007/BF02639664

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02639664

Keywords

Navigation