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The antioxidant properties of some 6-Hydroxychromans and 5-Hydroxycoumarans

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Journal of the American Oil Chemists Society

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Summary

The inhibitor activity of some 6-hydroxychromans and 5-hydroxycoumarans in gasoline and lard was investigated. The coumarans are the more effective in both substrates. Introduction of a tertiary butyl group ortho to the hydroxyl group increases the activity of 2,2-dimethyl-5-hydroxycoumaran in both substrates, but the activity of the 2,2-dimethyl-6-hydroxychromans is increased only in gasoline.

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References

  1. Olcott, H. S., and Emerson, O. H., J. Am. Chem. Soc.,59, 1008 (1937).

    Article  CAS  Google Scholar 

  2. Golumbic, C., J. Am. Chem. Soc.,63, 1142 (1941).

    Article  CAS  Google Scholar 

  3. Rosenwald, R. H., and Chenicek, J. A., U. S. Patent 2,310,710 (Feb. 9, 1943).

  4. Hurd, C. D., and Hoffman, W. A., J. Org. Chem.,5, 212 (1940).

    Article  CAS  Google Scholar 

  5. Gleim, W. K. T., and Chenicek, J. A., U. S. Patent 2,535,058 (Dec. 26, 1950); Gleim, W. K. T., U. S. Patent 2,546,499 (Mar. 27, 1951); and Gaydasch, A., and Gleim, W. K. T., U. S. Patent 2,681,371 (June 15, 1954).

  6. Riemenschneider, R. W., Juros, J., and Speck, R. M., Oil and Soap,20, 169 (1943).

    Article  CAS  Google Scholar 

  7. U. O. P. Laboratory Test Methods for Petroleum and Its Products, Chicago (1947).

  8. Waters, W. A., “The Chemistry of the Free Radicals,” Oxford (1946); and Waters, W. A., p. 168–169, “Le Mecanisnic de l’Oxidation,’ Brussels (1950).

  9. Pauling, L., and Wheland, G. W., J. Chem. Phys.,1, 367 (1933).

    Google Scholar 

  10. Ingold, C. K., “Structure and Mechanism in Organic Chemistry,” Cornell (1953).

  11. Rosenwald, R. H., and Chenicek, J. A., J. Am. Oil Chemists’ Soc.,28, 185 (1951).

    CAS  Google Scholar 

  12. Campbell, T. W., and Coppinger, G. M., J. Am. Chem. Soc.,74, 1469 (1952).

    Article  CAS  Google Scholar 

  13. Golumbic, C., Oil and Soap,20, 105 (1943).

    Article  CAS  Google Scholar 

  14. Boozer, C. E., and Hammond, G. S., J. Am. Chem. Soc.,76, 3861 (1954).

    Article  CAS  Google Scholar 

Download references

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Gleim, W.K.T., Chenicek, J.A. The antioxidant properties of some 6-Hydroxychromans and 5-Hydroxycoumarans. J Am Oil Chem Soc 33, 322–324 (1956). https://doi.org/10.1007/BF02639343

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  • DOI: https://doi.org/10.1007/BF02639343

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