Abstract
An acid-activated clay (Çanakkale montmorillonite from Turkey) was used to adsorb chlorophyll from hexane solutions. The phenomenon seems to be mainly driven by the interaction of chlorophyll with acid sites. The adsorption of chlorophyll on Brönsted acid sites was indicated by a characteristic infrared band for the -OH group at 3671 cm−1. The variations in the structure of clay mineral and chlorophyll during adsorption have been examined by differential thermal analysis, thermogravimetry and infrared spectroscopy of the activated clay before and after adsorption of chlorophyll. Oxidation of adsorbed chlorophyll was completed at quite a high temperature.
References
Daniel, S. (ed.)Bailey’s Industrial Oil and Fat Products, John Wiley and Sons, New York, NY, 1979, p. 69.
Siddiqui, M.K.H.,Bleaching Earths, Pergamon Press, London, England, 1968, p. 46.
Formo, M.W., E. Jungermann, F.A. Norris and N.O. Sonntag,Bailey’s Industrial Oil and Fat Products, edited by Dr. Swern, John Wiley and Sons, New York, NY, 1979, Vol. 1, p. 72.
Heyding, R.D., R. Ironside, A.R. Norris and R.Y. Prysiazniuk,Can. J. Chem. 38:1003 (1960).
Sarier N., Ph.D. Thesis, Izmir, Turkey, 1986.
Grim, R.E.,Applied Mineralogy, McGraw-Hill, New York, NY 1962, pp. 313, 322.
Hinners, H.F., J.J. McCarthy and R.E. Bass,Oil and Soap 23:22 (1946).
Rich, A.D.,J. Am. Oil Chem. Soc. 44:298A (1967).
Taylor, D.R., D.B. Jenkins and C.B. Ungerman, Ibid.:334 (1989).
Willstaetter, R., and A. Stoll,Untersuchungen über chlorophyll, Springer-Verlag, 1913, pp. 53, 251.
Sarier, N., and Ç. Güler,J. Am. Oil Chem. Soc. 65:776 (1988).
Sarier, N., and Ç. Guler, Ibid.:917 (1989).
Everett, D.H.,Trans. Faraday Soc. 60:1803 (1964).
Pritchett, W.C., W.G. Taylor and D.M. Carrol,J. Am. Oil Chem. Soc. 24:225 (1947).
Hair, M.L.,Infrared Spectroscopy in Surface Chemistry, Marcel Dekker Inc., New York, NY, 1967, pp. 79–137.
Güler, Ç., and N. Sarier,Doga-Tr. J. of Chemistry 15:1 (1991).
Taylor, D.R., and D.B. Jenkins,Society of Mining Engineering of the American Institute of Mechanical Engineers, Trans, 282:1901 (1988).
Morgan, D.A., D.B. Shaw, M.J. Sidebottm, J.C. Soon and R.S. Taylor,J. Am. Oil Chem. Soc. 62:292 (1985).
Author information
Authors and Affiliations
About this article
Cite this article
Güler, Ç., Tunç, F. Chlorophyll adsorption on acid-activated clay. J Am Oil Chem Soc 69, 948–950 (1992). https://doi.org/10.1007/BF02636350
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02636350