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Thermal decompositions of some divalent transition metal complexes of triethanolamine

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Abstract

The thermal behaviours of the Ti(II), Mn(II), Fe(II), Ni(II), Cu(II) and Zn(II) complexes of triethanolamine were studied by means of thermogravimetry, differential thermogravimetry, differential thermal analysis infrared spectrophotometry and elemental analysis. The sequence of thermal stability of the metal complexes, determined by using the initial decomposition temperature, was found to be Ti(II)≅Mn(II)>Fe(II)>Ni(II)>Zn(II)>Cu(II). Some of the kinetic parameters, such as the activation energy and order of reaction for the initial decomposition reaction, were calculated and the relationship between the thermal stability and the chemical structure of the complexes is discussed.

Zusammenfassung

Mittels TG, DTG, IR-Spektrofotometrie und Elementaranalyse wurde das thermische Verhalten der Ti(II)-, Mn(II)-, Fe(II)-, Ni(II)-, Cu(II)-, und Zn(II)- Komplexe von Triethanolamin untersucht. Die anhand der Temperatur für die einsetzende Zersetzung ermittelte Reinhenfolge für die thermische Stabilität der Metallkomplexe lautet: Ti(II)≅Mn(II)>Fe(II)>Ni(II)>Zn(II)>Cu(II). Einige der kinetischen Parameter, wie Aktivierungsenergie und Reaktionsordnung für die einsetzende Zersetzungsreaktion wurden berechnet und die Beziehung zwischen Stabilität und chemischer Struktur der Komplexe besprochen.

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References

  1. E. A. Allen, J. D. Gaudis and W. Wilkinson, Thermochim. Acta, 11 (1975) 197.

    Article  CAS  Google Scholar 

  2. A. Tatehata, T. Kumamaru and Y. Yamamoto, J. Inorg. Nucl. Chem., 33 (1971) 3427.

    Article  CAS  Google Scholar 

  3. W. W. Wendlandt, Analyt. Chim. Acta, 20 (1959) 270.

    Article  Google Scholar 

  4. W. W. Wendlandt and W. M. Hoffman, Analyt. Chem., 32 (1960) 1011.

    Article  CAS  Google Scholar 

  5. W. W. Wendlandt and J. P. Smith, Thermal Properties of Transition Metal Amine Complexes, Elsevier, Amsterdam 1967.

    Google Scholar 

  6. S. J. Ashcroft and C. T. Mortimer, Thermochemistry of Transition Metal Complexes, Academic Press, London 1970.

    Google Scholar 

  7. M. L. Kantouri, G. A. Katsoulos, C. C. Hadjikostas and P. Kokorotsikos, J. Thermal Anal., 35 (1989) 2411.

    Article  Google Scholar 

  8. H. B. Choudhari, L. J. Paliwal, P. D. Kichambare and R. B. Kharat, Bull. Soc. Chim. France, 2 (1989) 202.

    Google Scholar 

  9. H. E. Toma and L. A. Morino, J. Thermal Anal., 36 (1990) 7.

    Article  CAS  Google Scholar 

  10. R. Nagar and R. C. Sharma, J. Thermal Anal., 36 (1990) 181.

    Article  CAS  Google Scholar 

  11. J. O. Hill, Thermal Anal. Rev. Abst., Rev. No. 14, 20 (1991) 1.

    Google Scholar 

  12. B. Sen and R. L. Dotson, J. Inorg. Nucl. Chem., 32 (1970) 2707.

    Article  CAS  Google Scholar 

  13. A. Jeres, J. Thermal Anal., 26 (1983) 315.

    Article  Google Scholar 

  14. E. S. Freeman and B. Carroll, J. Phys. Chem., 62 (1958) 394.

    Article  CAS  Google Scholar 

  15. J. G. Stark and H. G. Wallace, John Murray Ltd., London, 1982.

  16. W. W. Wendlandt, J. H. Van Tassel and G. R. Horton, Analyt. Chim. Acta, 23 (1960) 332.

    CAS  Google Scholar 

  17. W. W. Wendlandt and G. R. Horton, Analyt. Chem., 34 (1962) 1098.

    Article  CAS  Google Scholar 

  18. M. N. H. Irving and R. J. P. Williams, J. Chem. Soc., 3192 (1953).

Download references

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences and Arts, Ondokuz Mayis University, 55139, Kurupelit, Samsun-Turkey

    H. Içbudak, V. T. Yilmaz & H. Ölmez

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  1. H. Içbudak
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  2. V. T. Yilmaz
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  3. H. Ölmez
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Içbudak, H., Yilmaz, V.T. & Ölmez, H. Thermal decompositions of some divalent transition metal complexes of triethanolamine. Journal of Thermal Analysis 44, 605–615 (1995). https://doi.org/10.1007/BF02636280

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  • DOI: https://doi.org/10.1007/BF02636280

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