Abstract
The excess heats of mixing of pyridine bases with toluene at 298.15 K were measured, and the Prigogine-Flory-Patterson theory was applied to describe the experimental results.
Zusammenfassung
Die molaren Überschussenthalpien binärer Mischungen von Pirydin, α-Picolin, 2,6-Lutidin, 2,4,6-Kollidin mit Toluol wurden bei 298.15 K im ganzen Zusammen-setzungsbereich gemessen. Die gemessenenH E Werte wurden mit denen verglichen, die mit Hilfe von Prigogine-Flory-Patterson Theorie berechnet worden waren.
Similar content being viewed by others
References
H. Wilczura, T. Kasprzycka-Guttman and S. Randzio, Bull. Pol. Acad. Sci. Chem., 34 (1986) 483.
T. Kasprzycka-Guttman and H. Wilczura, Thermochim. Acta, 158 (1990) 1.
T. Kasprzycka-Guttman, H. Wilczura and A. Myslinski, J. Thermal Anal., 38 (1992) 1357.
T. Kasprzycka-Guttman and H. Wilczura, Thermochim. Acta, 198 (1992) 405.
T. Kasprzycka-Guttman and H. Wilczura, Thermochim. Acta, 184 (1991) 321.
H. Wilczura, B. Semeniuk, A. Myslinski and T. Kasprzycka-Guttman, J. Thermal Anal., 38 (1992) 2011.
T. Kasprzycka-Guttman and H. Wilczura, Thermochim. Acta, 209 (1992) 25.
T. Kasprzycka-Guttman and H. Wilczura—in press.
T. Kasprzycka-Guttman and H. Wilczura—prepared for publication.
I. Prigogine, The Molecular Theory of Solutions, North Holland, Amsterdam 1957.
P. J. Flory, R. A. Orwoll and A. Vrij, J. Am. Chem. Soc., 86 (1964) 3507.
P. J. Flory, R. A. Orwoll and A. Vrij, J. Am. Chem. Soc., 86 (1964) 3515.
P. J. Flory, J. Am. Chem. Soc., 87 (1965) 1833.
A. Abe and P. J. Flory, J. Am. Chem. Soc., 87 (1965) 1838.
E. Eichinger and P. J. Flory, Trans. Faraday Soc., 64 (1968) 2035.
A. Heintz, Ber. Bunsen. Phys. Chem., 89 (1985) 172.
W. Woycicki and K. W. Sadowska, Bull. Acad. Pol. Sci., ser. Chim. XVI, 6 (1968) 329.
T. J. V. Findlay, Australian J. Chem., 14 (1961) 646.
J. C. Merlin and A. Ait-Kaci, Int. Data Ser., Selec. Data Mixtures, Ser. A. 1 (1982) 34.
A. Griot, R. Philippe and J. C. Merlin, J. Chim. Physique, 79 (1982) 671.
R. R. Dreisbach, Physical Properties of Chemical Compounds, American Chemical Society, Washington 1955.
K. Chreptowicz, Doctoral Thesis, University of Warsaw 1985.
H. Wilezura, Doctoral Thesis, University of Warsaw 1991.
P. J. Howell, B. J. Skillerne de Bristowe and D. Stubley, J. Chem. Soc. (A), (1971) 397.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Wilczura, H., Kasprzycka-Guttman, T. & Myslinski, A. Excess heat of mixing of pyridine bases with toluene. Journal of Thermal Analysis 44, 563–570 (1995). https://doi.org/10.1007/BF02636275
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02636275