Skip to main content
Log in

Excess heat of mixing of pyridine bases with toluene

Experimental results and theoretical description

  • Published:
Journal of thermal analysis Aims and scope Submit manuscript

Abstract

The excess heats of mixing of pyridine bases with toluene at 298.15 K were measured, and the Prigogine-Flory-Patterson theory was applied to describe the experimental results.

Zusammenfassung

Die molaren Überschussenthalpien binärer Mischungen von Pirydin, α-Picolin, 2,6-Lutidin, 2,4,6-Kollidin mit Toluol wurden bei 298.15 K im ganzen Zusammen-setzungsbereich gemessen. Die gemessenenH E Werte wurden mit denen verglichen, die mit Hilfe von Prigogine-Flory-Patterson Theorie berechnet worden waren.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. H. Wilczura, T. Kasprzycka-Guttman and S. Randzio, Bull. Pol. Acad. Sci. Chem., 34 (1986) 483.

    Google Scholar 

  2. T. Kasprzycka-Guttman and H. Wilczura, Thermochim. Acta, 158 (1990) 1.

    Article  CAS  Google Scholar 

  3. T. Kasprzycka-Guttman, H. Wilczura and A. Myslinski, J. Thermal Anal., 38 (1992) 1357.

    Article  CAS  Google Scholar 

  4. T. Kasprzycka-Guttman and H. Wilczura, Thermochim. Acta, 198 (1992) 405.

    Article  CAS  Google Scholar 

  5. T. Kasprzycka-Guttman and H. Wilczura, Thermochim. Acta, 184 (1991) 321.

    Article  CAS  Google Scholar 

  6. H. Wilczura, B. Semeniuk, A. Myslinski and T. Kasprzycka-Guttman, J. Thermal Anal., 38 (1992) 2011.

    Article  CAS  Google Scholar 

  7. T. Kasprzycka-Guttman and H. Wilczura, Thermochim. Acta, 209 (1992) 25.

    Article  CAS  Google Scholar 

  8. T. Kasprzycka-Guttman and H. Wilczura—in press.

  9. T. Kasprzycka-Guttman and H. Wilczura—prepared for publication.

  10. I. Prigogine, The Molecular Theory of Solutions, North Holland, Amsterdam 1957.

    Google Scholar 

  11. P. J. Flory, R. A. Orwoll and A. Vrij, J. Am. Chem. Soc., 86 (1964) 3507.

    Article  CAS  Google Scholar 

  12. P. J. Flory, R. A. Orwoll and A. Vrij, J. Am. Chem. Soc., 86 (1964) 3515.

    Article  CAS  Google Scholar 

  13. P. J. Flory, J. Am. Chem. Soc., 87 (1965) 1833.

    Article  CAS  Google Scholar 

  14. A. Abe and P. J. Flory, J. Am. Chem. Soc., 87 (1965) 1838.

    Article  CAS  Google Scholar 

  15. E. Eichinger and P. J. Flory, Trans. Faraday Soc., 64 (1968) 2035.

    Article  CAS  Google Scholar 

  16. A. Heintz, Ber. Bunsen. Phys. Chem., 89 (1985) 172.

    CAS  Google Scholar 

  17. W. Woycicki and K. W. Sadowska, Bull. Acad. Pol. Sci., ser. Chim. XVI, 6 (1968) 329.

    Google Scholar 

  18. T. J. V. Findlay, Australian J. Chem., 14 (1961) 646.

    Article  Google Scholar 

  19. J. C. Merlin and A. Ait-Kaci, Int. Data Ser., Selec. Data Mixtures, Ser. A. 1 (1982) 34.

    Google Scholar 

  20. A. Griot, R. Philippe and J. C. Merlin, J. Chim. Physique, 79 (1982) 671.

    CAS  Google Scholar 

  21. R. R. Dreisbach, Physical Properties of Chemical Compounds, American Chemical Society, Washington 1955.

    Google Scholar 

  22. K. Chreptowicz, Doctoral Thesis, University of Warsaw 1985.

  23. H. Wilezura, Doctoral Thesis, University of Warsaw 1991.

  24. P. J. Howell, B. J. Skillerne de Bristowe and D. Stubley, J. Chem. Soc. (A), (1971) 397.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wilczura, H., Kasprzycka-Guttman, T. & Myslinski, A. Excess heat of mixing of pyridine bases with toluene. Journal of Thermal Analysis 44, 563–570 (1995). https://doi.org/10.1007/BF02636275

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02636275

Keywords

Navigation