Abstract
X-ray diffraction patterns of a number of commercial bleaching earths indicate that they consist mainly of montmorillonite mixed with smaller amount of kaolinites as well as mica, quartz and cristobalite. The active sites in these earths for the adsorption of β-carotene are identified through ion exchange and found to be the protonic sites and some metallic ions. The efficiencies of the various cations in imparting activities to the earths are found to be in the order Mg2+ > Fe3+ > H+ > Ca2+ > Na+. For Fe3+ and H+ exchanged clays, the activity was found to be linear function of the concentration of these ions. The high activities of Mg2+ and Ca2+ exchanged clays are discussed.
Similar content being viewed by others
References
Grim, R.E., Applied Mineralogy, McGraw-Hill, New York, NY, 1962, pp. 322, 313.
Zschau, W., Bleaching of Palm Oil, Palm Oil Product Technologies in the Eighties Conference, Kuala Lumpur, Malaysia, 1981, paper TP3.
Brimberg, V.U.I., Fette Seifen Anstrichm. 83:184 (1981).
Rich, A.D., JAOCS 44:298A (1967).
Bruggemann, J., W. Krauss and J. Tiews, Naturwissenschaften 38:562 (1951).
Savinov, B.G., and A.A. Svishehuk, Ikr. Khim. Zhr 16:57 (1950).
Shaw, D.B., and G.K. Tribe, Use of Activated Earths in Palm Oil Refining and Their Effects on Trace Metals Contaminants, Palm Oil Product Technologies in the Eighties Conference, Kuala Lumpur, Malaysia, 1981, paper TP5.
Khoo, L.E., F. Morsingh and K.Y. Liew, JAOCS 56:672 (1979).
Hirschler, A.E., J. Catal. 2:428 (1963).
Carrol, D., Clay Minerals: A Guide to Their X-ray Identification, The Geology Soc. of America, 1974, special paper 126, USA.
Van Olphen, H., Proc. of Intern. Symp. on Surface Area Determination, Butterworths, London, 1969, p. 225.
Ward, J.W., J. Catal. 11:259 (1968).
Ward, J.W., Ibid. 10:34 (1968).
Author information
Authors and Affiliations
Additional information
Presented in part as paper T12 in the International Conference on Palm Oil Product Technologies in the Eighties, Kuala Lumpur, May 1981.
About this article
Cite this article
Liew, K.Y., Tan, S.H., Morsingh, F. et al. Adsorption of β-carotene: II. On cation exchanged bleaching clays. J Am Oil Chem Soc 59, 480–484 (1982). https://doi.org/10.1007/BF02636147
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02636147