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A new catalyst for the selective hydrogenation of sunflower seed oil

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Journal of the American Oil Chemists Society

Abstract

A new Ni catalyst supported on sepiolite has been prepared by the precipitation/deposition method. Its activity and selectivity was tested in the hydrogenation reaction of sunflower seed oil. The variables studied were active phase concentration, reaction temperature and stirring speed. For contrasting purposes, a commercial catalyst designed for the same objective by Süd Chemie A.G. (Munich, Germany), G-53, was also tested under the same set of conditions. Selectivity to oleic acid with the new catalyst was appreciably better. The activation energies obtained with both catalyst were of the same order and within the range of those found in the literature for conventional nickel catalysts.

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References

  1. Normann, W., British patent 1515 (1903).

  2. Anderson, K., L. Petersson and N.H. Schoon,Acta Polytech. Scan. Chem. Ind. Met. Ser. 100:77 (1971).

    Google Scholar 

  3. Wisniak, J., and L.F. Albright,Ind. Eng. Chem. 53:375 (1961).

    Article  CAS  Google Scholar 

  4. Hashimoto, K., M. Teramoto, and J. Negata,Chem. Eng. Jpn. 4:150 (1971).

    CAS  Google Scholar 

  5. Patterson, H.B.W.,Hydrogenation of Fats and Oils, Applied Science Publishers, Ltd., London, England, 1983, pp. 6–10.

    Google Scholar 

  6. Köseoglu, S.S., and E.W. Lusas,J. Am. Oil Chem. Soc. 67:39 (1990).

    Article  Google Scholar 

  7. Hsu, N., L.L. Diosady and L.J. Rubin, Ibid.:349 (1988).

    CAS  Google Scholar 

  8. Gut, G., J. Kosinka, A. Prabucki and A. Schuerch,Chem. Eng. Sci. 34:1051 (1979).

    Article  CAS  Google Scholar 

  9. Coenen, W.E.,Ind. Eng. Chem. Fundam. 25:53 (1986).

    Article  Google Scholar 

  10. Grau, R.J., A.E. Cassano and M.A. Baltanás,Catal. Rev. Sci. Eng. 30:1 (1988).

    CAS  Google Scholar 

  11. Muñoz, V., and S. Mendioroz,Appl. Catal. 66:73 (1990).

    Article  Google Scholar 

  12. Van Dillen, J.A., J.W. Geus, L.A.M. Hermans and J. van der Meijden,Proceedings of 6th International Congress on Catalysis, London, England, 1976, p. 67.

  13. Langmuyr, F.J., and P.E. Paus,An. Chim. Acta 43:397 (1968).

    Article  Google Scholar 

  14. Metcalfe, L.D., and C.N. Wang,Chromatogr. Sci. 19:530 (1981).

    CAS  Google Scholar 

  15. Susu, A.A., A.F. Ogunye and Ch. Onyegbado,J. Appl. Chem. Biotechnol. 28:823 (1978).

    CAS  Google Scholar 

Download references

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Rodrigo, M.T., Mendioroz, S. A new catalyst for the selective hydrogenation of sunflower seed oil. J Am Oil Chem Soc 69, 802–805 (1992). https://doi.org/10.1007/BF02635919

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  • DOI: https://doi.org/10.1007/BF02635919

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