Skip to main content
Log in

Identification of decomposition products from autoxidation of methyl 4,7,10,13,16,19-docosahexaenoate

  • Technical
  • Published:
Journal of the American Oil Chemists Society

Abstract

This is a continuation of a previous publication in which a number of aldehydes, aldehyde esters, hydrocarbons, and methyl esters was identified among the oxidation products of methyl docosahexaenoate. In the present paper, the identification of certain keto-esters, unsaturated ketones, cyclic esters, and furan derivatives also is reported. Mechanisms for the formation of these compounds are proposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Noble, A.C., and W.W. Nawar, JAOCS 48:800 (1971).

    Article  CAS  Google Scholar 

  2. Kawada, T., R. Krishnamurthy, B. Mookherjee, and S. Chang, Ibid. 44:131 (1967).

    Article  CAS  Google Scholar 

  3. Noble, A.C., and W.W. Nawar, J. Can. Inst. Food Technol. 4:135 (1971).

    CAS  Google Scholar 

  4. Budzikiewicz, H., C. Djerassi, and D. Williams, “Mass Spectrometry of Organic Compounds,” Holden-Day, San Francisco, Calif., 1967.

    Google Scholar 

  5. Ryhage, R., And E. Stenhagen, Arkiv Kemi 15:545 (1960).

    CAS  Google Scholar 

  6. Rohwedder, W., A. Mabrouk, and E. Selke, J. Phys. Chem. 69:1711 (1965).

    CAS  Google Scholar 

  7. Wantland, L., and E. Perkins, Lipids 5:191 (1970).

    Article  CAS  Google Scholar 

  8. Yamanishi, T., M. Nose, and Y. Nakatani, Ag. Biol. Chem. (Japan) 34:599 (1970).

    CAS  Google Scholar 

  9. Bondarovich, H., A. Giammarino, J. Renner, F. Shephard, A. Shingler, and M. Gianturco, Agr. Food Chem. 15:36 (1967).

    Article  CAS  Google Scholar 

  10. Heyns, K., R. Stute, and H. Scharmann, Tetrahedron 22:2223 (1966).

    Article  CAS  Google Scholar 

  11. Chang, S., T. Smouse, R. Krishnamurthy, B. Mookerjee, and R. Reddy, Chem. Ind. 46:1926 (1966).

    PubMed  CAS  Google Scholar 

  12. Kawase, Y., Y. Ohta, H. Niizuma, and K. Yasuda, J. Jap. Oil Chem. Soc. 18:738 (1969).

    CAS  Google Scholar 

  13. Begemann, P.H., W. Woestenberg, and S. Leer, Paper presented at the American Chemical Society Meeting, Chicago, September, 1967.

  14. Hutchison, R., and J. Alexander, J. Org. Chem. 28:2522 (1963).

    CAS  Google Scholar 

  15. Michael, W., Lipids 1:359 (1966).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

About this article

Cite this article

Noble, A.C., Nawar, W.W. Identification of decomposition products from autoxidation of methyl 4,7,10,13,16,19-docosahexaenoate. J Am Oil Chem Soc 52, 92–95 (1975). https://doi.org/10.1007/BF02633045

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02633045

Keywords

Navigation