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The preparation and properties of some synthetic glycerides

II. control of the migration of acyl groups

  • Technical
  • Published:
Journal of the American Oil Chemists Society

Abstract

In a study of the use of tritylglycerols as starting materials for synthesis of mono- or diglycerides and mixed triglycerides, it was found that acyl migration can be minimized or prevented by detritylation in petroleum ether, avoiding contact with polar solvents or contaminants. Under conditions favoring acyl migration, tetrabromostearoyl radicals were found to migrate less readily than stearoyl radicals.

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Author information

Authors and Affiliations

  1. State University College, Geneseo, New York

    J. E. Jackson

  2. The Hormel Institute, University of Minnesota, Austin, Minnesota

    W. O. Lundberg

Authors
  1. J. E. Jackson
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  2. W. O. Lundberg
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Additional information

From thesis submitted by J. E. Jackson in partial fulfillment of requirements for the Ph.D. degree, University of Minnesota, 1958. This work was supported in part by a grant from the Archer-Daniels-Midland Co.

Publication No. 4265, Agricultural Experiment Station, University of Minnesota.

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Jackson, J.E., Lundberg, W.O. The preparation and properties of some synthetic glycerides. J Am Oil Chem Soc 40, 502–504 (1963). https://doi.org/10.1007/BF02632847

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  • DOI: https://doi.org/10.1007/BF02632847

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