Summary
Volatile cleavage products of autoxidizing methyl linolenate have chromatographically separated and the aldehydes have been isolated as 2,4-dinitrophenylhydrazones. Acetaldehyde, propionaldehyde, and α-pentenal have been identified. A six-carbon atom dialdehyde has been isolated as its hydrazone and is postulated to be hexene-3-dial-1,6.
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Delaby, M. R., and Guillot-Allegré, S., Bull. soc. chim. France,53, 301 (1933).
Dutton, H. J., Lancaster, Catherine R., Evans, C. D., and Cowan, J. C., J. Am. Oil Chem. Soc.,28, 115–118 (1951).
Farmer, E. H., Koch, H. P., and Sutton, D. A., J. Chem. Soc.,1943, 541–547.
Fugger, J., Cannon, J. C., Zilch, K. T., and Dutton, H. J., J. Am. Oil Chem. Soc.,28, 285–289 (1951).
Fugger, J., Zilch, K. T., Cannon, J. A., and Dutton, H. J., J. Am. Chem. Soc.,73, 2861–2864 (1951).
Gunstone, F. D., and Hilditch, T. P., J. Am. Oil Chem. Soc.,29, 372–377 (1952).
Kawahara, F. K., and Dutton, H. J., J. Am. Oil Chem. Soc.,29, 372–377 (1952).
Martin, C. J., Schepartz, A. I., and Daubert, B. F., J. Am. Chem. Soc.,70, 2601–2602 (1948).
Schepartz, A. I., and Daubert, B. F., J. Am. Oil Chem. Soc.,27, 367–373 (1950).
Stapf, R. J., and Daubert, B. F., J. Am. Oil Chem. Soc.,27, 374–377 (1950).
Stirton, A. J., Turer, J., and Riemenschneider, R. W., Oil and Soap, 22, 81–83 (1945).
Strain, H. H., J. Am. Chem. Soc.,57, 758–761 (1935).
Swift, C. E., O'Connor, R. T., Brown, L. E., and Dollear, F. G., J. Am. Oil Chem. Soc.,26, 297–300 (1949).
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One of the laboratories of the Bureau of Agricultural and Industrial Chemistry, Agricultural Research Administration, U. S. Department of Agriculture. Report of a study made under the Research and Marketing Act of 1946.
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Kawahara, F.K., Dutton, H.J. & Cowan, J.C. Volatile cleavage products of autoxidized methyl linolenate. J Am Oil Chem Soc 29, 633–635 (1952). https://doi.org/10.1007/BF02631731
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DOI: https://doi.org/10.1007/BF02631731