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Tweed structures associated with Fcc-Fct transformations in Fe-Pd alloys

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Abstract

The tweed microstructure associated with fcc-fct martensitic transformation in Fe-Pd alloys containing about 30 at. pct Pd was investigated by transmission electron microscopy and the selected area diffraction. It was observed that the tweed contrast consisting of {011}/<01ī> striations and accompanying the diffuse streaks became distinct from a temperature nearly 100 K above the Ms with lowering temperature. The tweed contrast was found to be induced by the static displacement of atoms, δ{011}/[01ī], associated with the formation of disc-shaped martensite nuclei on the {110} planes of the austenite. The tweed microstructure persistently remained in the fct martensite in the early stage of the transformation, where the degree of tetragonality is small and the c-axis directions of the small fct martensite variants are tilted against each other, giving rise to the tweed pattern. A similar tweed contrast observed in the initial stage of ordering in a stoichiometric Fe-Pd alloy was also explained by a strain contrast effect arising from an elastic shear strain induced by the nucleation of short range order particles with tetragonal distortion.

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This paper is based on a presentation made in the symposium “Pretransformation Behavior Related to Displacive Transformations in Alloys” presented at the 1986 annual AIMS meeting in New Orleans, March 2–6, 1986. under the auspices of the ASM-MSD Structures Committee.

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Oshima, R., Sugiyama, M. & Fujita, F.E. Tweed structures associated with Fcc-Fct transformations in Fe-Pd alloys. Metall Trans A 19, 803–810 (1988). https://doi.org/10.1007/BF02628361

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