Summary
A number of soaps from hydrogenated fat stocks having good and bad characteristics as emulsifiers in plant production of GR-S were analyzed for nickel, copper, and iron. A statistical study of the data on polymerization and metal contents indicated that variability in conversion was associated with variations in the metal content of the soap.
Similar content being viewed by others
References
Alexander, O. R., Godar, E. M., and Linde, N. J., Ind. Eng. Chem., Anal. Ed.,18, 206 (1946).
Bacon, R. G. R., Trans. Faraday Soc.,42, pt. 3/4, 140 (1946); Baxendale, J. H., Evans, M. G., and Park, G. S.,Ibid., p. 155; Morgan, L. B.,Ibid., p. 169.
Ault, W. C., Brice, B. A., Swain, M. L., Schaeffer, B. B., and Copley, M. J., J. Am. Oil Chem. Soc.,26, 700 (1949).
Brice, B. A., and Swain, M. L., Opt. Soc. Am.,35, 532 (1945).
Brice, B. A., Swain, M. L., Schaeffer, B. B., and Ault, W. C., Oil and Soap,22, 219 (1945).
Burke, O. W. Jr., Presented at meeting of American Oil Chem. Soc., Chicago, Ill., November 7, 1945. See also Semon, W. L., J. Am. Oil Chem. Soc.24, 33 (1947).
Ezekiel, M., “Methods of Correlation Analysis,” 2nd Ed., 1941. John Wiley, New York City, Chapter 12, p. 190.
Hummel, F. O., and Willard, H. H., Ind. Eng. Chem., Anal. Ed.,10, 13 (1938).
Kenney, J. F., “Mathematics of Statistics,” Part I, pp. 170–175.
Lingane, J. J., and Kerlinger, H., Ind. Eng. Chem., Anal. Ed.,13, 77 (1941).
Palfrey, G. F., Hobert, R. H., Benning, A. F., and Dobratz, I. W., Ind. Eng. Chem., Anal. Ed.,12, 94 (1940).
Reynolds, C. A., and Rogers, L. B., Anal. Chem.,21, 176 (1949).
Author information
Authors and Affiliations
Additional information
One of the laboratories of the Bureau of Agricultural and Industrial Chemistry, Agricultural Research Administration, U. S. Department of Agriculture.
About this article
Cite this article
Brice, B.A., Ricciuti, C., Willits, C.O. et al. Relationship between nickel content of soap and conversion to polymer in manufacture of synthetic rubber (GR-S). J Am Oil Chem Soc 28, 85–87 (1951). https://doi.org/10.1007/BF02612198
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02612198