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Quadrupolar interaction in iridium cyanide mixed-ligands complexes in alkali halide matrices by ESR spectroscopy

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Abstract

Quadrupolar interactions in [IR(CN)5]3−, [Ir(CN)5Cl]4− and [Ir(CN)4Cl2]4− paramagnece a complexes in alkali halide host lattices are systematically analysed by ESR spectroscopy. The measured quadrupolar interactions are shown to have no clear correlation to the measured unpaired electron populations.

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Authors and Affiliations

  1. Instituto de Fisica, Universidade Federal do Rio de Janeiro, Ilha do Fundão, Cidade Universitária, Bloco A, C.T., 21945, Rio de Janeiro, Brazil

    N. M. Pinhal & N. V. Vugman

Authors
  1. N. M. Pinhal
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  2. N. V. Vugman
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Pinhal, N.M., Vugman, N.V. Quadrupolar interaction in iridium cyanide mixed-ligands complexes in alkali halide matrices by ESR spectroscopy. Hyperfine Interact 52, 89–95 (1989). https://doi.org/10.1007/BF02609565

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  • DOI: https://doi.org/10.1007/BF02609565

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