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Estimation of the value of ΔR/R for121Sb nucleus by means of Mössbauer spectroscopy and molecular orbital calculation

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Abstract

The121Sb Mössbauer spectra of rapidly frozen solutions of antimony compounds were observed. The isomer shifts were compared with the electron density at the antimony nucleus calculated with the ab initio molecular orbital method. A value ΔR/R=−(11±2)×10−4 was derived for the 37.15 keV M1 transition of121Sb.

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References

  1. H. Muramatsu, T. Miura, H. Nakahara, M. Fujioka, E. Tanaka and A. Hashizume, Hyp. Int. 20(1984)305.

    Article  Google Scholar 

  2. T. Miura, Y. Hatsukawa, M. Yanaga, K. Edo, H. Nakahara, M. Fujioka, E. Tanaka and A. Hashizume, Hyp. Int. 28(1986)857;Hyp. Int. 30(1986)371.

    Article  Google Scholar 

  3. V. Gutman,The Donor-Acceptor Approach to Molecular Interactions (Plenum Press, New York, 1978) Ch. 2.

    Google Scholar 

  4. M. Takahashi, R. Ohayama and M. Takeda, to be published.

  5. M. Takeda, M. Takahashi, R. Ohyama and I. Nakai, Hyp. Int. 28(1986)741.

    Article  Google Scholar 

  6. A. Lipka, Acta Cryst. B35(1979)3020.

    Article  Google Scholar 

  7. S. Huzinaga, ed.,Gaussian Basis Sets for Molecular Science (Elsevier, Amsterdam, 1984).

    Google Scholar 

  8. W.J. Hehre, R.F. Stewart and J.A. Pople, J. Chem. Phys. 51(1969)2657.

    Article  Google Scholar 

  9. A. Stromberg, O. Gropen and U. Wahlgren, J. Comput. Chem. 4(1983)181.

    Article  Google Scholar 

  10. T.H. Dunning, Jr. and P.J. Hay, in:Modern Theoretical Chemistry, Vol. 3, ed. H.F. Schaefer III (Plenum Press, New York, 1977) Ch. 1.

    Google Scholar 

  11. P.G. Mezey, M.H. Lien, K. Yates and I.G. Csizmadia, Theor. Chim. Acta (Berlin) 40(1975)75.

    Article  Google Scholar 

  12. H. King, M. Duouis and J. Rys, Nat. Resour. Comput. Chem. Software Cat., Vol. 1, Prog. No. QH02 (HONDO5), 1980.

  13. D.A. Shirley, Rev. Mod. Phys. 36(1964)339.

    Article  ADS  Google Scholar 

  14. I.M. Band and V.I. Fomichev, Atom. Data and Nucl. Data Tables 23(1979)295.

    Article  ADS  Google Scholar 

  15. S.L. Ruby, G.M. Kalvius, G.B. Beard and R.E. Snyder, Phys. Rev. 159(1967)239.

    Article  ADS  Google Scholar 

  16. V.A. Bryukhanov, B.Z. Iofa, V. Kothekar, S.I. Semenov and V.S. Shpinel, Zh. Eksp. Teor. Fiz. 53(1967)1582, [Sov. Phys. JETP 26(1968)912].

    Google Scholar 

  17. V. Kothekar, B.Z. Iofa, S.I. Semenov and V.S. Shpinel, Zh. Eksp. Teor. Fiz. 55(1968) 160, [Sov. Phys. JETP 28(1969)86].

    Google Scholar 

  18. R.A. Pruitt, S.W. Marshall and C.M. O'Donnell, Phys. Rev. B2(1970)2383.

    Article  ADS  Google Scholar 

  19. D.I. Baltrunas, S.P. Ionov, A.Yu. Aleksandrov and E.F. Makarov, Chem. Phys. Lett. 20 (1973)55.

    Article  ADS  Google Scholar 

  20. V. Kothekar, Int. J. Quant. Chem. 10(1976)993.

    Article  Google Scholar 

  21. W. Ravenek, J.W.M. Jacobs and A. v.d. Avoird, Chem. Phys. 78(1983)391.

    Article  Google Scholar 

  22. A. Svane and E. Antoncik, J. Phys. C20(1987)2683.

    Article  ADS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Tokyo Metropolitan University, Funasawa, Setagaya-ku, 158, Tokyo, Japan

    Makoto Yanaga, Kazutoyo Endo & Hiromichi Nakahara

  2. Department of General Education, Tokyo Metropolitan University, Yakumo, Meguro-ku, 152, Tokyo, Japan

    Shigeru Ikuta

  3. National Laboratory for High Energy Physics, Oho, Tsukuba-shi, 305, Ibaraki, Japan

    Taichi Miura

  4. Department of Chemistry, Faculty of Science, Toho University, Miyama, Funabashi-shi, 274, Chiba, Japan

    Masashi Takahashi & Masuo Takeda

Authors
  1. Makoto Yanaga
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  2. Kazutoyo Endo
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  3. Hiromichi Nakahara
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  4. Shigeru Ikuta
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  5. Taichi Miura
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  6. Masashi Takahashi
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  7. Masuo Takeda
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Yanaga, M., Endo, K., Nakahara, H. et al. Estimation of the value of ΔR/R for121Sb nucleus by means of Mössbauer spectroscopy and molecular orbital calculation. Hyperfine Interact 52, 147–151 (1989). https://doi.org/10.1007/BF02609554

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  • DOI: https://doi.org/10.1007/BF02609554

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