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Geochemistry of some volcanic rocks from south-eastern sicily: Rare earth and other trace element distribution

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Abstract

Some trace element data for volcanic rocks found at different levels, from Tertiary to Holocene, in south-eastern Sicily (Iblean Plateau and Mt. Etna) are presented and discussed in the present paper in order to better the information about the origin and relationships of the various rock types.

Four groups of volcanic rocks have been recognized on the basis of their major element chemistry: 1) low-K tholeiites, 2) associated alkali basalts to nephelinites of the Iblean Plateau (Upper Pliocene to Lower Pleistocene), 3) the basal subalkaline lavas of Mt. Etna, and 4) the alkalic suite rocks that make up the bulk of the volcano.

The distribution of Rb, Sr, Ni, Cr, Co, Cu, REE, Th and Sc suggests:

  1. i)

    an origin of the Iblean magmas by a different degree of partial melting of a Rb-poor and possibly slightly hetereogeneous mantle;

  2. ii)

    quite distinct source compositions for the Etnean magmas, relative to those of the Iblean area, on the basis of their Rb and Sr contents;

  3. iii)

    an origin of the alkalic rocks of Mt. Etna from independently generated magma(s) rather than by crystal fractionation of the Etnean subalkaline magmas or of a magma having the geochemical features of the Iblean alkali basalts; evidence for this is given by the distribution features of the incompatible elements showing an origin for these rocks from compositionally different parent magmas and/or an evolution under widely variable environmental conditions;

  4. iv)

    the primary character for the chemical differences observed in some of the Etnean subalkaline rocks that can be accounted for by different physico-chemical conditions at their source rather than by crystal fractionation processes.

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References

  • Albini, A., De Cillis, D. andStanzione, D., 1976,Dati preliminari sull’analisi mediante attivazione neutronica delle terre rare in campioni di rocce dell’USGS. Rend. Accad. Sci. Fis. Mat. Soc. Naz. Sci. Lett. Arti Napoli, Ser. 4,43, p. 1–14.

    Google Scholar 

  • Barberi, F., Bizouard, H., Capaldi, G., Ferrara, G., Gasparini, P., Innocenti, F., Joron, J.L., Lambret, B., Treuil, M., Allegre, C., 1977,Age and Nature of Basalts from the Tyrrhenian Abyssal Plain. In Repts. DSDP,42,p. 509–514.

    Google Scholar 

  • —————, 1974a,Evolution of a Section of the Africa-Europe Plate Boundary: Paleomagnetic and Volcanological Evidence from Sicily. Earth Plan. Sci. Lett.,22, p. 123–132.

    Article  Google Scholar 

  • ————— andVillari L., 1974b,Evolution of the Aeolian Arc Volcanism (Southern Tyrrhenian Sea). Earth Plan. Sci. Lett.,21, p. 269–176.

    Article  Google Scholar 

  • Battaglia, M., Cristofolini, R., Di Girolamo, P. andStanzione, D., 1976,Rare Earth Element and Other Trace Element Distribution, and the Origin of the Iblean Magmas. Jour. Volcan. Geotherm. Res.,1,, p. 331–346.

    Article  Google Scholar 

  • Bottari, A., Lo Giudice, E., Patane, G., Romano, R. andSturiale, C., 1975,L’eruzione etnea del gennaio-marzo 1974. Riv. Miner. Sic.154–156, p. 175–198.

    Google Scholar 

  • Carter, S.R., andCivetta, L., 1977,Isotope and Trace Element Variations in the Eastern Sicilian Volcanics: Genetic Implications of the Heterogeneous Nature and Development of the Source Regions. Earth Plan. Sci. Lett.36, p. 168–180.

    Article  Google Scholar 

  • Cristofolini, R., 1966a, Le manifestazioni eruttive basiche del Trias superiore nel sottosuolo di Ragusa (Sicilia sud-orientale). Per. Miner.35, p. 1–28.

    Google Scholar 

  • —————, 1966b, Studio petrografico del più profondo livello vulcanico nel sottosuolo (dolomia triassica) di Ragusa. Atti Accad. Gioenia Sci. Nat. Ser. 6,18, p. 29–48.

    Google Scholar 

  • —————, 1971,La distribuzione del titanio nelle vulcaniti etnee. Per. Miner.40, p. 41–66.

    Google Scholar 

  • —————, 1972,I basalti a tendenza tholeiitica dell’Etna. Per. Miner.41, p. 167–200.

    Google Scholar 

  • —————, 1973,Recent Trends in the Study of Etna. Phil. Trans. Roy. Soc. Lond.,A 274, p. 17–35.

    Google Scholar 

  • —————, 1975,La massa subvulcanica di Acitrezza (Etna). Rc. Soc. Ital. Miner. Petr.30, p. 741–770.

    Google Scholar 

  • —————, andBattaglia, M., 1975,Le manifestazioni basaltiche della zona di Francofonte nel quadro del vulcanismo dell’Altopiano Ibleo. Boll. Soc. Geol. Ital.,94, p. 185–207.

    Google Scholar 

  • ————— andVezzani, L., 1977a,Neotectonics, Seismicity and Volcanic Activity in Northeastern Sicily. VI Colloq. Geol. Aegean Reg., Proc.,2, p. 757–766.

    Google Scholar 

  • ————— andLo Giudice, A., 1969,Le latitandesiti di un complesso intermedio tra il Trifoglietto ed il Mongibello affiorante tra la Valle del Bove ed Adrano-Biancavilla (Etna). Rc. Soc. Ital. Miner. Petr.,25, p. 227–261.

    Google Scholar 

  • ————— andTranchina, A., 1977b, Il basso versante nord-orientale dell’Etna nei dintorni di Piedimonte Etneo: studio geologico e morfostrutturale. Boll. Soc. Geol. Ital.,96, p. 695–712.

    Google Scholar 

  • ————— andPuglisi, D., 1975,Caratteri petrografici dell’affioramento basaltico di Motta S. Anastasia (Etna). Rc. Soc. Ital. Miner. Petr.,30, p. 771–800.

    Google Scholar 

  • ————— and —————, 1976,Rapporti petrogenetici tra lave porfiriche ed afiriche del basso versante meridionale dell’Etna. Boll. Soc. Geol. Ital.,94, p. 1297–1322.

    Google Scholar 

  • ————— andSpadea, P., 1975,Le lave latitandesitiche antiche della zona di Piedimonte Etneo (versante nord-orientale dell’Etna). Rc. Soc. Ital. Miner. Petr.,31, p. 309–336.

    Google Scholar 

  • Dietrich, V., Emmermann, R., Keller, J. andPuchelt, H., 1977,Tholeiitic Basalts from the Tyrrhenian Sea Floor. Earth Plan. Sci. Lett.,36, p. 285–296.

    Article  Google Scholar 

  • Di Grande, A., 1972,Geologia dell’area a Nord di Augusta-Francofonte (Sicilia SE). Atti Accad. Gioenia Sci. Nat. Ser. 7,4, p. 1–32

    Google Scholar 

  • Drake, M.J. andWeill, D.F., 1975,Partition of Sr, Ba, Ca, Y, Eu 2+, Eu3+, and Other REE between Plagioclase Feldspar and Magmatic Liquid: an Experimental Study. Geochim. Cosmochim. Acta,39, p. 689–712.

    Article  Google Scholar 

  • Duncan, A.M., 1976,Petrology and Geology of the Volcanic Rocks of the Adrano Area. Mount. Etna, Sicily. Ph. D. Thesis. Univ. Lond.

  • Frey, F.A., Bryan, W.B. andThompson G., 1974,Atlantic Ocean Floor: Geochemistry and Petrology of Basalts from Legs 2 and 3 of the Deep-Sea Drilling Project. Jour. Geoph. Res.,79, p. 5507–5527.

    Google Scholar 

  • —————, andHaskin, L.A., 1968,Rare Earth Abundances in Some Basic Rocks. Jour. Geoph. Res.,73, p. 6085–6098.

    Article  Google Scholar 

  • Gast, P.W., 1968,Trace Element Fractionation and the Origin of the Alkaline and Tholeiitic Magma Types. Geochim. Cosmochim. Acta,32, p. 1057–1086.

    Article  Google Scholar 

  • Higuchi, H. andNagasawa, H., 1969,Partition of Trace Elements between Rock-forming Minerals and the Host Volcanic Rocks. Earth Plan. Sci. Lett.,7, p. 281–287.

    Article  Google Scholar 

  • Hubbard, N.J., 1969,A Chemical Comparison of Oceanic Ridge, Hawaiian Tholeiitic and Hawaiian Alkalic Basalts. Earth Plan. Sci. Lett.,5, p. 346–352.

    Article  Google Scholar 

  • Kempe, D.R.C. andSchilling, J.C., 1974,Discovery Tablemountain Basalt: Petrology and Geochemistry. Contrib. Miner. Petr.,44, p. 101–116.

    Article  Google Scholar 

  • Nakamura, N., 1974,Determination of REE, Ba, Fe, Mg, Na and K in Carbonaceous and Ordinary Chondrites. Geochim. Cosmochim. Acta,38, p. 757–775.

    Article  Google Scholar 

  • Ogniben, L., Martinis, B., Rossi, P.M., Fuganti, A., Pasquare, G., Sturani, C., Nardi, R., Cocozza, T., Praturlon, A., Parotto, M., D’Argenio, B., Pescatore, T., Scandone, P., Vezzani, L., A.G.I.P., Finetti, I., Morelli, C., Caputo, M., Postpischl, D. andGiese, P., 1974,Modello strutturale d’Italia, Scale 1:1,000,000. C.N.R., Rome.

  • O’Nions, R.K., Pankhurst, R.J. andGronvold, K., 1976,Nature and Development of Basalt Magma Sources beneath Iceland and the Reykjanes Ridge. Jour. Petr.,17, p. 315–338.

    Google Scholar 

  • Ottonello, G. andRanieri, G., 1977,Effetti del controllo petrogenetico sulla distribuzione del bario nel processo di anatessi crustale. Rc. Soc. Ital Miner. Petr.,33, p. 741–753.

    Google Scholar 

  • Poli, G., Manetti, O., Peccerillo, A. andCecchi, A., 1977,Determinazione di alcuni elementi del gruppo delle terre rare in rocce silicatiche per attivazione neutronica. Rc. Soc. Miner. Petr.33, p. 755–763.

    Google Scholar 

  • Ponte, G., 1916,La formazione vulcanica sottomarina di Capo Passero. Atti Accad. Gioenia Sci. Nat. Ser. 5,9, p. 1–62.

    Google Scholar 

  • Price, R.C., andChappell, B.W., 1975,Fractional Crystallisation and the Petrology of Dunedin Volcano. Contrib. Miner. Petr.,53, p. 157–182.

    Article  Google Scholar 

  • Prinz, M., 1967,Geochemistry of Basaltic Rocks: Trace Elements. InHess, H.H., &Poldervaart, A. (eds.)Basalts. Wiley-Interscience, New York, p. 271–323.

    Google Scholar 

  • Puglisi, D. andTranchina, A., 1977,Variazioni petrografiche e petrochimiche entro due successioni laviche affioranti sul versante nord-orientale dell’Etna (zona di Piedimonte Etneo). Miner. Petr. Acta,21, p. 65–91.

    Google Scholar 

  • Romano, R. andVillari, L., 1973,Caratteri petrologici e magmatologici del vulcanismo Ibleo. Rc. Soc. Ital. Miner. Petr.,29, p. 453–483.

    Google Scholar 

  • Schilling, J.C., 1973a,Iceland Mantle Plume: Geochemical Study of Reykjanes Ridge. Nature,242, p. 565–571.

    Article  Google Scholar 

  • —————, 1973b,Afar Mantle Plume: Rare Earth Evidence. Nature Phys. Sci.,242, p. 2–5.

    Google Scholar 

  • ————— andWinchester, J.W., 1969,Rare Earth Contribution to the Origin of Hawaiian Lavas. Contrib. Miner. Petr.,23, p. 27–37.

    Article  Google Scholar 

  • Schnetzler, C.C. andPhilpotts, J.A., 1970,Partition Coefficients of Rare Earth Elements and Barium between Igneous Matrix Material and Rock-forming Mineral Phenocrysts — II. Geochim. Cosmochim. Acta,34, p. 331–341.

    Article  Google Scholar 

  • Shaw, D.M., 1970,Trace Element Fractionation during Anatexis. Geochim. Cosmochim. Acta,34, p. 237–243.

    Article  Google Scholar 

  • Shimizu, N. andArculus, R. J., 1975,Rare Earth Concentrations in a Suite of Basanitoids and Alkali Olivine Basalts from Grenada, Lesser Antilles. Contrib. Miner. Petr.50, p. 231–240.

    Article  Google Scholar 

  • Tanguy, J.C., 1978,Tholeiitic Basalt Magmatism of Mount Etna and Its Relations with the Alkaline Series. Contrib. Miner. Petr.,66, p. 51–67.

    Article  Google Scholar 

  • Treuil, M. andJoron, J. L., 1975,Utilisation des éléments hygromagmatophiles pour la semplification de la modelisation quantitative des processus magmatiques. Examples de l’Afar e de la dorsale medio-Atlantique. Rc. Soc. Ital. Miner. Petr.,31, p. 125–174.

    Google Scholar 

  • ————— andVaret, J., 1973,Critères volcanologiques, pétrologiques et géochimiques de la génèse et de la differenciation des magmas basaltiques, example de l’Afar. Bull. Soc. Géol. Fr., Ser. 7,15, p. 506–540.

    Google Scholar 

  • Zielinski, R.A., 1975,Trace Element Evaluation of a Suite of Rocks from Reunion Island, Indian Ocean. Geochim. Cosmochim. Acta,39, p. 713–734.

    Article  Google Scholar 

  • Yoder, H.S., Jr., 1976,Generation of Basaltic Magma. Nat. Acad. Sci., Washington, 264 pp.

    Google Scholar 

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Authors and Affiliations

  1. Istituto di Scienze della Terra, C.so Italia 55, Catania, Italy

    R. Cristofolini

  2. C.I.S.E., Segrate, Milan, Italy

    A. Albini

  3. Istituto di Mineralogia, Via Mezzocannone 8, Naples, Italy

    P. Di Girolamo & D. Stanzione

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  1. R. Cristofolini
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  2. A. Albini
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  3. P. Di Girolamo
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  4. D. Stanzione
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Work supported by C.N.R. (Grant 77.01134.05)

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Cristofolini, R., Albini, A., Di Girolamo, P. et al. Geochemistry of some volcanic rocks from south-eastern sicily: Rare earth and other trace element distribution. Bull Volcanol 44, 95–107 (1981). https://doi.org/10.1007/BF02598191

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