Skip to main content
SpringerLink
Log in

Composition, structure, and ir spectra of acid trialkylmethylammonium acetates in CCl4+HAc solutions

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The composition and structure of neutral and acid trialkyl(C8-C10)methylammonium acetates in CCl4+HAc solutions formed by the reaction R3CH3N+Ac−+nHAc⇔R3CH3N+(Ac·nAc)− are investigated by IR spectroscopy. As the molar ratio HAc/R3CH3N+Ac− increases in solutions, complex anions Ac·nAc− (I) with n=1, 2, 3, 4 are formed in sequence. The curves of formation of anions with n=0, 1, 2 are plotted. One terminal COO group of anions I is bonded to (“blocked” by) the R3CH3N+ cation, and another group sequentially adds H-bonded HAc molecules as the concentration of HAc in solutions increases. The sequence of IR spectral changes in the series of anions I with n=0, 1, 2, 3, 4 is discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. C. Speakman,Struct. Bond.,12, 141–199 (1972).

    CAS  Google Scholar 

  2. G. B. Deacon and R. J. Philips,Coord. Chem. Rev.,33, No. 3, 227–250 (1980).

    Article  CAS  Google Scholar 

  3. D. Hadzi, M. Obradovic, and B. Orel,J. Mol. Struct.,14, No. 3, 439–450 (1972).

    Article  CAS  Google Scholar 

  4. D. Hadzi and B. Orel, ——ibid.,18, No. 2, 227–239 (1973).

    Article  CAS  Google Scholar 

  5. J. Baran, M. M. Ilczyczyn, et al., ——ibid.,246, 1–12 (1991).

    Article  CAS  Google Scholar 

  6. A. Novak, J. Bellor, E. Foglizzo, and F. Romain,J. Chim. Phys. 69, No. 11/12, 1615–1625 (1972).

    Google Scholar 

  7. D. Hadzi, B. Orel, and A. Novak,Spectrochim. Acta A29, No. 9, 1745–1753 (1973).

    Google Scholar 

  8. R. Lindemann and G. Zundel,J. Chem. Soc., Faraday Trans. 2,68, 979–990 (1972).

    Article  CAS  Google Scholar 

  9. G. V. Gusakova, G. S. Denisov, A. L. Smolyanskii, and V. M. Shraiber,Dokl. Akad. Nauk SSSR,193, No. 5, 1065–1068 (1970).

    CAS  Google Scholar 

  10. E. S. Stoyanov,Zh. Neorg. Khim.,35, No. 5, 1127–1133 (1990).

    CAS  Google Scholar 

  11. V. P. Glazunov, A. A. Mashkovskii, and S. S. Odinokov,Zh. Prikl. Spektrosk.,22, No. 4, 696–702 (1975).

    CAS  Google Scholar 

  12. M. Kakihana, T. Nagumo, M. Okamoto, and H. Kakihana,J. Phys. Chem.,91, 6128–6136 (1987).

    Article  CAS  Google Scholar 

  13. M. Hawrie and A. Novak,J. Chim. Phys.,62, No. 2, 146 (1965).

    Google Scholar 

Download references

Authors
  1. E. S. Stoyanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. A. Chesalov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Institute of Catalysis, Siberian Branch, Russian Academy of Sciences. Novosibirsk State University. Translated fromZhurnal Strukturnoi Khimii, Vol. 37, No. 2, pp. 310–318, March–April, 1996.

Translated by L. Smolina

Rights and permissions

Reprints and permissions

About this article

Cite this article

Stoyanov, E.S., Chesalov, Y.A. Composition, structure, and ir spectra of acid trialkylmethylammonium acetates in CCl4+HAc solutions. J Struct Chem 37, 270–277 (1996). https://doi.org/10.1007/BF02591057

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02591057

Keywords

Search

Navigation