Abstract
Commercial oleic acid has a tendency to develop a dark color during heating. It has been found that this discoloration is partially due to oxidation and partially due to the presence of minor constituents. Their characterization as oxidized and polymerized fatty acids will be reported in a separate paper. The effects of the two factors are synergistic to each other and thus accentuate the darkening of the commercial oleic acid when it is heated under air. Removal of the minor constituents from commercial oleic acid by silicic acid treatment drastically improved its color stability. The generally acknowledged concept that the higher the polyunsaturated fatty acid content in the commercial oleic acid, the lower its color stability, is not correct. The color stability of commercial oleic acid is more predominantly dependent upon the content of minor constituents than that of polyunsaturated fatty acid.
Similar content being viewed by others
References
Chang, S.S., “Basic Studies on the Color and Odor Stabilities of Commercial Fatty Acids Through the Isolation and Identification of Minor Constituents,” Final Report to Eastern Regional Research Center on Grant No. 12-14-100-9893(73), ARS, USDA, Philadelphia, PA, 1971.
Min, D.B.S., S.S. Lin, and S.S. Chang, JAOCS 52:28 (1975).
“Official and Tentative Methods of the American Oil Chemists’ Society,” Vol. I & II, 3rd Edition, AOCS, Champaign, IL, 1973 (revised annually), Method Td 2a-64.
Sahasrabudhe, M.R., and D.G. Chapman, JAOCS 38:88 (1961).
Author information
Authors and Affiliations
Additional information
Paper of the Journal Series, New Jersey Agricultural Experiment Station, Cook College, Rutgers, The State University of New Jersey.
Present address: Anderson Clayton Foods, Box 63, Richardson, TX 75080.
Present address: Quaker Oats Co., 617 W. Main St., Barrington, IL 60010.
About this article
Cite this article
Lin, S.S., Hsieh, A.L., Min, D.B.S. et al. A study of the color stability of commercial oleic acid. J Am Oil Chem Soc 53, 157–161 (1976). https://doi.org/10.1007/BF02586356
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02586356