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Amine-malonaldehyde condensation products and their relative color contribution in the thiobarbituric acid test

  • Technical
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Journal of the American Oil Chemists’ Society

Abstract

Different malonaldehyde-amine condensation products were tested for their relative color contribution to the thiobarbituric acid (TBA) test, an indicator for oxidative rancidity of polyunsaturated lipids. The open chain mono- and disubstituted malonaldehyde (M) addition products (R-N=CH-CH=CHOH and R-N=CH-CH=CH-NH-R) gave complete (100%) recovery ofM on a mole basis. When theM residue was incorporated into cyclic products which formed between the ureido- or guanidino- substituents of α-amino acids such as citrulline or arginine andM, recovery ofM by the TBA color test was 30% and 6%, respectively. Products, from imine-amine type interactions, containing theM residue as in pyrazoline or pyrazole ring systems, released from 4% to noM.

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Authors and Affiliations

  1. Fisheries Research Board of Canada, 6640 N.W. Marine Drive, Vancouver 8, B.C.

    H. Buttkus & R. J. Bose

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  1. H. Buttkus
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  2. R. J. Bose
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Buttkus, H., Bose, R.J. Amine-malonaldehyde condensation products and their relative color contribution in the thiobarbituric acid test. J Am Oil Chem Soc 49, 440–443 (1972). https://doi.org/10.1007/BF02582530

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  • DOI: https://doi.org/10.1007/BF02582530

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