Abstract
Raman scattering spectra are measured for lead-zirconate-titanate piezoceramics with measurements performed at varying temperatures and with exposure of the surface to atomic hydrogen. In order to investigate the kinetics of interaction of the ceramic surface with atomic hydrogen, the fixed-frequency time dependences of Raman scattering intensities are obtained as well. These dependences were analyzed and the activation energy of heterogeneous reduction reaction at the surface both for kinetics-controlled and for the diffusion-limited modes of the process were derived. The possibility of studying the kinetics of heterogeneous reduction reactions by an analysis of the time dependence for a fixed-frequency Raman signal intensity is demonstrated.
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References
F. F. Vol’kenstein,Electronic Processes at Semiconductor Surface in Chemisorption [in Russian], Nauka, Moscow (1987).
A. S. Belanovskii,Adsorption and Desorption at Semiconductor Surfaces [Reviews on Electronic Technology, Ser. Microelectron., No. 58] [in Russian], Elektronika, Moscow (1969).
V. Yu. Kireev, B. S. Danilin, and V. I. Kuznetsov,Plasma-Assisted and Ion-Beam-Induced Chemical Etching of Microstructures [in Russian], Radio i Svyaz’, Moscow (1983).
I. L. Roikh and L. N. Koltunova,Protective Vacuum-Deposited Coatings for Steel [in Russian], Mashinostroenie, Moscow (1971).
V. A. Bernshtein, V. P. Zaitseva, V. V. Nikitin, and V. A. Zharov,Fiz. Khim. Obrab. Mater., No. 4, 147 (1979).
V. A. Gengrinovich and I. L. Roikh,Elektron. Tekh., Ser. 10, No. 6, 53 (1969).
I. L. Roikh, V. A. Zharov, and O. N. Gorelova,Elektron. Obrab. Mater., No. 6, 31 (1976).
I. L. Roikh, V. A. Zharov, and O. N. Gorelova,Elektron. Obrab. Mater., No. 2, 70 (1977).
N. Hannay,Solid State Chemistry, Prentice Hall, Englewood Cliffs (1967).
F. K. McTaggart,Plasmochemistry in Electrical Discharge, Elsevier, Amsterdam, London, New York (1962).
A. N. Gorban’ and Yu. A. Shvets, in:Abstracts of the Topical Workshop on Surface Diagnostics with Ion Beams [in Russian], Zaporozh’e, 1983, p. 141.
A. Ya. Rozovskii,Kinetics of Topochemical Reactions [in Russian], Khimiya, Moscow (1974).
P. Barret,Cinetique Heterogene, Ganthier Villar, Paris (1973).
V. G. Kornich, V. P. Pinchuk, and A. N. Gorban’,Izv. Vyssh. Uchebn. Zaved., Fiz., No. 3, 107 (1975).
S. P. Lushchin and A. N. Gorban’, in:Abstracts of the 2nd Soviet Union Workshop on Chemiluminescence [in Russian], Ufa, 1986, p. 22.
L. I. Avramenko,Zh. Fiz. Khim.,20, 1299 (1946).
V. P. Pinchuk, A. N. Gorban’, and V. G. Kornich,Zh. Tekh. Fiz.,44, 1287 (1974).
A. N. Titov, V. P. Pinchuk, and A. N. Gorban’, in:Abstracts of the Soviet Union Workshop on Chemiluminescence [in Russian], Zaporozh’e, 1976, p. 174.
A. N. Gorban’ and V. M. Matyushin,Pisma Zh. Tekh. Fiz.,6, 482 (1986).
M. I. Pravda, V. M. Matyushin, and S. D. Tochilin, in:Theory and Practice of Reliability and Quality Control in Radio-Electronics [in Russian], Vysshee Obrazovanie, Kiev (1992), p. 136.
E. M. Omel’yanobskii and A. Ya. Polyakov,Vysokochist. Veschestva, No. 5, 15 (1988).
S. P. Lushchin and V. N. Zinchenko, in:Abstracts of the Soviet Union Workshop on Diagnostics of Surfaces with Ion Beams [in Russian], Uzhgorod, 1985, p. 98.
G. I. Chufarov and E. P. Tatievskaya, in:Problems in Metallurgy [in Russian], Nauka, Moscow (1953), p. 15.
S. T. Rostovtsev, in:Physicochemical Foundations of Metallurgical Processes [in Russian], Nauka, Moscow (1969), p. 5.
B. I. Kitaev, V. I. Timofeev, B. L. Bokovikov, et al.,Heat Exchange in a Dense Layer [in Russian], Metallurgiya, Moscow (1972).
V. P. Elyutin, Yu. A. Pavlov, V. P. Polyakov, et al.,Interaction of Metal Oxides with Carbon [in Russian], Metallurgiya, Moscow (1976).
E. S. Vorontsov, in:Physicochemical Foundations of Steel Production [in Russian], Nauka, Moscow (1971), p. 154.
E. S. Vorontsov, in:Mechanisms and Kinetics of Metal Reduction [in Russian], Nauka, Moscow (1970), p. 56.
V. V. Prisedskii, L. G. Klevtsova, and V. V. Kitov,Izv. Akad. Nauk, Neorg. Mater.,10, 2166 (1974).
V. I. Lyashenko, V. G. Litovchenko, I. I. Stepko, et al.,Electronic Phenomena at Semiconductor Surfaces [in Russian], Naukova Dumka, Kiev (1968).
K. Hauffe,Reaktionen in und un Festern Stoffen, Band II, Springer Verlag, Berlin, Gottingen (1955).
V. S. Gorelik and B. S. Umarov,Introduction to the Spectroscopy of Raman Scattering in Crystals [in Russian], Donish, Dushanbe (1982).
E. V. Angerer,Technische Kunstgriffe bei Physikalischen Untersuchungen, Vieweg, Braunschweig (1959).
V. A. Lavrenko,Recombination of Hydrogen Atoms at Solid Surfaces [in Russian], Naukova Dumka, Kiev (1973).
F. F. Vol’kenshtein, A. N. Gorban’, and V. A. Sokolov,Luminescence in Semiconductors due to Recombination of Radicals [in Russian], Nauka, Moscow (1976).
M. M. Sushchinskii,Proceedings of the Lebedev Physical Institute,180, Nauka, Moscow (1987), p. 20.
B. F. Ormont,An Introduction to Physical Chemistry and Crystal Chemistry of Semiconductors [in Russian], Vysshaya Shkola, Moscow (1982).
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Translated from a manuscript of the P. N. Lebedev Physical Institute, Russian Academy of Sciences.
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Gorelik, V.S., Lushchin, S.P. & Tochilin, S.D. Laser raman spectroscopy of lead-zirconate-titanate ceramics during exposure to atomic hydrogen. J Russ Laser Res 16, 414–426 (1995). https://doi.org/10.1007/BF02581225
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DOI: https://doi.org/10.1007/BF02581225