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Crystal structure investigation of ternary molybdate K5(Mn0.5Zr1.5).(MoO4)6

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Abstract

Crystals of K5(Mn0.5Zr1.5).(MoO4)6 were grown, and the crystal structure of this compound was refined in an X-ray diffraction study (CAD-4 automatic diffractometer, MoKα radiation, 1183 |F(hkl)|, R=0.027). The parameters of the trigonal unit cell are: a=b=10.584(1); c=37.576(3) Å; V=3645.4(3) Å3; space group R3c; dcalc=3.606 g/cm3. In the structure, the altermating Mo tetrahedra and (Mn, Zr) octahedra form a three-dimensional mixed framework whosevoids contain potassium atoms of three types. The distribution of the Mn and Zr cations in two crystallographic positions has been refined.

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Authors
  1. R. F. Klevtsova
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  2. Zh. G. Bazarova
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  3. L. A. Glinskaya
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  4. B. G. Bazarov
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  5. K. N. Fedorov
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  6. P. V. Klevtsov
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Additional information

Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences. Institute of Natural Sciences, Siberian Branch, Russian Academy of Sciences. Translated fromZhurnal Struktumoi Khimii, Vol. 36, No. 5, pp. 895–899, September–October, 1995.

Translated by L. Smolina

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Klevtsova, R.F., Bazarova, Z.G., Glinskaya, L.A. et al. Crystal structure investigation of ternary molybdate K5(Mn0.5Zr1.5).(MoO4)6 . J Struct Chem 36, 813–817 (1995). https://doi.org/10.1007/BF02579674

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  • DOI: https://doi.org/10.1007/BF02579674

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