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Crystal structure investigation of ternary molybdate K(Mg0.5Zr0.5).(MoO4)2

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Abstract

Crystals of K(Mg0.5Zr0.5).(MoO4)2 were grown, and the composition and crystal structure of the compound were refined in an X-ray diffraction study (CAD-4 automatic diffractometer, MoKα radiation, 475 F(hkl), R=0.022). The parameters of the trigonal unit cell are: a=5.763(1); c=7.187(1) Å,Z=1, space group P3m1. A typical feature of a glaserite-like structure is atomic arrangement in two layers: at z=0 the Mg and Zr atoms are statistically distributed in the oxygen octahedra, and at z=0.5 the K atoms are distributed inside the icosahedra. In the second layer, Mo atoms with tetrahedral environment are also distributed.

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Authors
  1. R. F. Klevtsova
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  2. Zh. G. Bazarova
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  3. L. A. Glinskaya
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  4. V. I. Alekseev
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  5. S. I. Arkhincheeva
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  6. B. G. Bazarov
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  7. P. V. Klevtsov
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Additional information

Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences. Institute of Natural Sciences, Siberian Branch, Russian Academy of Sciences. Translated fromZhurnal Struktumoi Khimii, Vol. 36, No. 5, pp. 891–894, September–October, 1995.

Translated by L. Smolina

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Klevtsova, R.F., Bazarova, Z.G., Glinskaya, L.A. et al. Crystal structure investigation of ternary molybdate K(Mg0.5Zr0.5).(MoO4)2 . J Struct Chem 36, 809–812 (1995). https://doi.org/10.1007/BF02579673

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  • DOI: https://doi.org/10.1007/BF02579673

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