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Homo- and heterochirality of dissymmetric tetrahedra (chiral simplices). Stereochemical tunneling

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Abstract

This paper examines the possibility of classifying chiral simplices into homochiral subclasses. It is shown that chiral simplices can skip achiral intermediates to be transformed into another type of homochiral moleucles (stereochemical tunneling).

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References

  1. V. I. Sokolov,Introduction to Theoretical Chemistry [in Russian], Nauka, Moscow (1973).

    Google Scholar 

  2. E. Ruch,Theor. Chim. Acta,11, No. 1, 183–189 (1968).

    Article  CAS  Google Scholar 

  3. K. Mislow and P. Poggi-Corradini,J. Math. Chem.,13, No. 2, 209–211 (1993).

    Article  Google Scholar 

  4. V. E. Kuzmin,Zh. Fiz. Khim.,68, No. 6 1037–1043 (1994).

    Google Scholar 

  5. V. E. Kuzmin, L. P. Trigub, I. V. Yudanova, et al.Chirality [in press].

  6. IUPAC Chemical Nomenclature [in Russian], Vol. 3, VINITI Moscow (1983).

  7. V. A. Nikanorov,Abstracts of Papers from the 5th All-Union Conference on Crystal Chemistry, Chernoglovka (1987), pp. 13, 191.

  8. V. E., Kuzmin and I. B. Stelmakh,Zh. Strukt. Khim,28, 45 (1987).

    CAS  Google Scholar 

  9. V. E. Kuzmin, I. B. Stelmakh, D. V. Pozigun, and M. B. Bekker,J. Phys. Org. Chem.,5, 293 (1992).

    Google Scholar 

  10. D. I. Blokhinstev,Basic Quantum Mechanics [in Russian], Nauka, Moscow (1976).

    Google Scholar 

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Additional information

A. V. Bogatskii Physiochemical Institute, Ukrainian Academy of Sciences. Translated fromZhurnal Strukturnoi Khimii, Vol. 36, No. 5, pp. 873–878, September–October, 1995.

Translated by L. Smolina

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Kuzmin, V.E. Homo- and heterochirality of dissymmetric tetrahedra (chiral simplices). Stereochemical tunneling. J Struct Chem 36, 793–797 (1995). https://doi.org/10.1007/BF02579670

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  • DOI: https://doi.org/10.1007/BF02579670

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