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Gas phase electron diffraction study of the hafnium perchlorate molecule

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Abstract

The structure of the Hf(ClO4)4 molecule was investigated by electron diffractometry in the gas phase. The model with D4 symmetry is in best agreement with experimental data; it contains ClO4 fragments in the form of distorted tetrahedra bridged by two oxygen atoms to the central Hf atom.

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Ivanovo Chemical Technological Academy. Moscow State University, Chemical Faculty. Translated fromZhurnal Strukturnoi Khimii, Vol. 37, No. 3, pp. 487–493, May-June, 1996.

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Lapshina, S.B., Ermolaeva, L.I., Girichev, G.V. et al. Gas phase electron diffraction study of the hafnium perchlorate molecule. J Struct Chem 37, 425–430 (1996). https://doi.org/10.1007/BF02578595

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  • DOI: https://doi.org/10.1007/BF02578595

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