Abstract
The structure of the Hf(ClO4)4 molecule was investigated by electron diffractometry in the gas phase. The model with D4 symmetry is in best agreement with experimental data; it contains ClO4 fragments in the form of distorted tetrahedra bridged by two oxygen atoms to the central Hf atom.
Similar content being viewed by others
References
V. P. Babaeva and V. Ya. Rosolovskii,Izv. Akad. Nauk SSSR, Ser. Khim., No. 3, 495–498 (1977).
V. P. Babaeva and V. Ya. Rosolovskii, ibid., No. 11, 2414–2418 (1974).
V. P. Babaeva and V. Ya. Rosolovskii,Zh. Neorg. Khim.,24, No. 2, 371–374 (1979).
A. V. Dudin, V. P. Babaeva, and V. Ya. Rosolovskii, ibid.,26, No. 11, 2933–2936 (1981).
S. P. Konovalov, G. V. Girichev, K. S. Krasnov, and V. P. Spiridonov,Abstracts of Papers from the 7th All-Union Conference, Kishinev (1980), pp. 82–83.
J. V. Silverton and J. L. Hoard,Inorg. Chem.,2, No. 2, 243–249 (1963).
W. Clegg,Acta Crystallogr. C,43, No. 4, 789–791 (1987).
A. V. Demidov, L. I. Ermolaeva, E. Z. Zasorin, and A. V. Golubinskii,Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol.,35, No. 11/12, 129–131 (1992).
Yu. S. Ezhov, S. A. Komarov, V. G. Sevast'yanov, et al.,Vysokochist. Veshchest., No. 5, 103–110 (1993).
V. P. Spiridonov, E. Z. Zasorin, A. A. Ishchenko et al.,10th International Symposium on Crystallography, Amsterdam (1975), p. 272.
A. H. Clark, B. Beagley, D. W. J. Cruissherk, et al.,J. Chem. Soc. A, No. 9, 1613 (1970).
Yu. Sh. Kalaichev, Candidate's Dissertation, Moscow Physical Technical Institute, Moscow (1984).
O. P. Charkin,Stability and Structure of Gas-Phase Inorganic Molecules, Radicals, and Ions [in Russian], Nauka, Moscow (1980).
Thermodynamic Properties of Individual Substances [in Russian], Handbook, Vol. 3, Nauka, Moscow (1981).
N. I. Giricheva, G. V. Girichev, V. M. Petrov, et al.,Zh. Strukt. Khim.,29, No. 5, 46–53 (1988).
Q. Chen, Ph. D. Thesis, Oregon University (1974).
N. I. Giricheva, G. V. Girichev, V. A. Titov, et al.,Zh. Strukt. Khim.,33, No. 4, 50–59 (1992).
G. V. Girichev and N. I. Giricheva, ibid.,28, No. 4, 189–191 (1987).
V. M. Petrov, N. I. Giricheva, and V. N. Petrova, ibid.,32, No. 4, 51–55 (1991).
Additional information
Ivanovo Chemical Technological Academy. Moscow State University, Chemical Faculty. Translated fromZhurnal Strukturnoi Khimii, Vol. 37, No. 3, pp. 487–493, May-June, 1996.
Rights and permissions
About this article
Cite this article
Lapshina, S.B., Ermolaeva, L.I., Girichev, G.V. et al. Gas phase electron diffraction study of the hafnium perchlorate molecule. J Struct Chem 37, 425–430 (1996). https://doi.org/10.1007/BF02578595
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02578595