Skip to main content
SpringerLink
Log in

Synthesis, structure, and magnetic properties of mixed-ligand complexes of manganese and gadolinium hexafluoroacetylacetonates with 4-phenyl-2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl nitroxide

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Complexes of manganese(II) and gadolinium(III) hexafluoroacetylacetonates with stable nitroxide 4-phenyl-2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl (L), Mn(hfac)2L2 and Gd(hfac)3L2, have been synthesized. The results of an X-ray study of these complexes (Mn(hfac)2L2: a=21.762(4), b=9.685(1), c=22.073(3) Å, β=114.94(1)°, space group Cc, Z=4; Gd(hfac)3L2: a=22.079(4), b=11.562(2), c=21.302(4) Å, β=112.25(1)°, space group Cc, Z=4) have shown that both compounds have a molecular structure with the paramagnetic ligand coordinated via the oxygen atom of the N-oxide group. According to the results of static magnetic susceptibility measurements, the energies of exchange interactions between unpaired electrons of L and of metal ions are less than 1 cm−1 in magnitude.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. Caneschi, D. Gatteschi, and P. Rey,Prog. Inorg. Chem.,89, 331–350 (1991).

    Article  Google Scholar 

  2. V. I. Ovcharenko,Synthetic Chemistry of Stable Imidazoline Nitroxides, CRC Press, Boca Raton, FL (1994), pp. 159–219.

    Google Scholar 

  3. A. Caneschi, D. Gatteschi, P. Rey, and R. Sessoli,Inorg. Chem.,27, 1756–1761 (1988).

    Article  CAS  Google Scholar 

  4. A. Caneschi, D. Gatteschi, L. Pardi, P. Rey, et al.,ibid. Inorg. Chem., 2027–2032.

  5. A. Caneschi, D. Gatteschi, J. Laugier, and P. Rey,J. Am. Chem. Soc.,110, 2795–2799 (1988).

    Article  CAS  Google Scholar 

  6. C. Benelli, A. Ganeschi, D. Gatteschi, et al.,Angew. Chem., 958–959 (1987).

  7. F. A. Cotton and R. H. Holm,J. Am. Chem. Soc.,82, 2979–2983 (1960).

    Article  CAS  Google Scholar 

  8. M. F. Richardson, W. F. Wagner, and D. E. Sands,J. Inorg. Nucl. Chem.,30, 1275–1290 (1968).

    Article  CAS  Google Scholar 

  9. G. M. Sheldrick,SHELX-86, in:Crystallographic Computing 3, G. M. Sheldrick, C. Kruger, and R. Goddard (eds.), Oxford University Press, London (1987), pp. 175–189.

    Google Scholar 

  10. G. M. Sheldrick,SHELX-76. A Program for Crystal Structure Determination, Cambridge (1976).

  11. L. B. Volodarskii, I. A. Grigoriev, S. A. Dikanov, et al., in:Imidazoline Nitroxides [in Russian] Nauka, Novosibirsk (1988), p. 90.

    Google Scholar 

  12. L. M. Shkolnikova and M. A. Porai-Koshits,Itogi Nauki Tekh., Ser. Kristallokhim., Vol. 16, 117–125 (1982).

    CAS  Google Scholar 

  13. R. S. Drago, T. C. Kuechler, and M. Kroeger,Inorg. Chem.,18, 2333–2337 (1979).

    Google Scholar 

  14. R. S. Drago, G. C. Vogel, and T. Needham,J. Am. Chem. Soc.,93, 6014–6026 (1971).

    Article  CAS  Google Scholar 

  15. R. G. Pearson, —ibid.,85, 3533–3539 (1963).

    Article  CAS  Google Scholar 

  16. S. J. Gruber, C. M. Harris, and E. Sinn,J. Chem. Phys.,49, 2183–2194 (1968).

    Article  CAS  Google Scholar 

  17. A. P. Ginsberg and M. E. Lines,Inorg. Chem.,11, 2289–2290 (1972).

    Article  CAS  Google Scholar 

  18. A. Caneschi, D. Gatteschi, and P. Rey,Prog. Inorg. Chem.,89, 331–370 (1991).

    Article  Google Scholar 

Download references

Authors
  1. A. B. Burdukov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. V. Pervukhina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. N. Ikorskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. I. Ovcharenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

International Tomography Center, Siberian Branch, Russian Academy of Sciences. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences. Translated fromZhurnal Strukturnoi Khimii, Vol. 36, No. 3, pp. 518–527, May–June, 1995.

Translated by L. Smolina

Rights and permissions

Reprints and permissions

About this article

Cite this article

Burdukov, A.B., Pervukhina, N.V., Ikorskii, V.N. et al. Synthesis, structure, and magnetic properties of mixed-ligand complexes of manganese and gadolinium hexafluoroacetylacetonates with 4-phenyl-2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl nitroxide. J Struct Chem 36, 474–483 (1995). https://doi.org/10.1007/BF02578535

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02578535

Keywords

Search

Navigation