Abstract
An analysis of the microwave spectrum of acetyl chloride (12CH3 12C16O35Cl) in the ground vibrational state allowed us to determine the quartic constants of centrifugal distortion and to refine the rotational constants and the constants of quadrupole coupling of35Cl nuclei in this compound. The Stark effect of the 0–111 transition has been measured and analyzed. The components of the dipole moment have been determined: μa=1.047(10) D and μb=2.503(4) D. The total dipole moment of the moment of the molecule is 2.713(8) D.
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Additional information
Ufa Scientific Center of Russian Academy of Sciences, Physics Department. Translated fromZhurnal Struktumoi Khimii, Vol. 36, No. 3, pp. 424–429, May–June, 1995.
Translated by I. Izvekova
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Galeev, R.V., Gunderova, L.N., Mamleev, A.K. et al. Microwave spectrum, centrifugal perturbation, and dipole moment of acetyl chloride. J Struct Chem 36, 386–391 (1995). https://doi.org/10.1007/BF02578524
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DOI: https://doi.org/10.1007/BF02578524