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Copper(I) nitrate π-complexes. Synthesis and crystal structure of the first CuNo3 π-complex with diallylamine of equimolar composition

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Abstract

We have carried out synthesis and X-ray structural study (DARCH, MoKα radiation, graphite monochromator, ϕ/2ϕ, scan mode, 2ϕ<-65°) of the CuNo3·C6H11N π-complex (a=14.346(6), c=16.719(7) δA, space group I41/a, and Z=16). The bifunctional (bridge and chelate) tridentate molecule of diallylamine cross-links the inorganic component into infinite spirals oriented along the axes 41 and 43. The mainly covalent character of the Cu+...No -3 bond affects the hydrogen bond strength and the efficiency of the metal-olefin interaction.

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Authors
  1. M. G. Myskiv
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  2. E. A. Goreshnik
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  3. V. K. Pecharskii
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  4. V. V. Oljinik
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Additional information

I. Franko Lvov State University. Translated fromZhumal Strukturmoi Khimii, Vol. 35, No. 1, pp. 90–94, January–February, 1994.

Translated by T. Yudanova

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Myskiv, M.G., Goreshnik, E.A., Pecharskii, V.K. et al. Copper(I) nitrate π-complexes. Synthesis and crystal structure of the first CuNo3 π-complex with diallylamine of equimolar composition. J Struct Chem 35, 82–86 (1994). https://doi.org/10.1007/BF02578504

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  • DOI: https://doi.org/10.1007/BF02578504

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