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X-ray fluorescent and EXAFS studies of the electronic and spatial structure of dialkyl sulfides and their PdCl2 complexes in extraction systems

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Abstract

SKα, SKβ, ClKβ, ClKβ, and PdLβ2 X-ray fluorescent and PdK EXAFS spectra were obtained for some organic solutions of dialkyl sulfide complexes with palladium chloride. Solvent effects on the electronic and spatial structure of complexes in solution are discussed. In the benzene solution of [PdCl22(C6H13)2S], complex molecules interact with solvent molecules along a coordinate that is perpendicular to the plane of the complex molecule.

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Authors
  1. S. B. Érenburg
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  2. L. N. Mazalov
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  3. N. V. Bausk
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  4. M. K. Drozdova
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Additional information

Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences. Translated fromZhurmal Strukturnoi Khimii, Vol. 35, No. 4, pp. 105c111, July–August, 1994.

Translated by L. Smolina

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Érenburg, S.B., Mazalov, L.N., Bausk, N.V. et al. X-ray fluorescent and EXAFS studies of the electronic and spatial structure of dialkyl sulfides and their PdCl2 complexes in extraction systems. J Struct Chem 35, 517–522 (1994). https://doi.org/10.1007/BF02578363

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  • DOI: https://doi.org/10.1007/BF02578363

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