Abstract
We have synthesized high-spin mixed-ligand Mn2+ complexes Mn(S2COR)2L where R=i−C3H7, i−C4H9; [L=1,10-phenanthroline (Phen), 2,2′-bipyridyl (2,2′-Bipy), 4,4′-bipyridyl (4,4′-Bipy)]. As solids, the compounds are stable to oxidation by atmospheric oxygen. An X-ray structural study of the [Mn(S2COC3H7−i)2(2,2′-Bipy)] complex was carried out. The structure is composed of discrete monomeric molecules. The corrdination polyhedron of the Mn atom is a distorted [4S+2N] octahedron. The molecules are bonded by van der Waals interactions.
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Additional information
Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences. Translated fromZhurnal Strukturnoi Khimii, Vol. 35, No. 2, pp. 106–111, March–April, 1994.
Translated by T. Yudanova
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Kirichenko, V.N., Glinskaya, L.A., Klevtsova, R.F. et al. Synthesis of mixed-ligand managanese(II) complexes with alkyl xanthate ions and nitrogen-containing heterocycles. Crystal and molecular structure of the [Mn(S2COC3H7−i )2(2,2′-Bipy)] complex. J Struct Chem 35, 242–247 (1994). https://doi.org/10.1007/BF02578315
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DOI: https://doi.org/10.1007/BF02578315